GA1, Me-TMS

• Formula: C₂₆H₄₂O₆Si₂
• Molecular weight: 506.7791
• IUPAC Standard InChI: InChI=1S/C26H42O6Si2/c1-16-14-24-15-25(16,32-34(7,8)9)12-10-17(24)26-13-11-18(31-33(4,5)6)23(2,22(28)30-26)20(26)19(24)21(27)29-3/h17-20H,1,10-15H2,2-9H3/t17?,18-,19?,20?,23+,24-,25-,26+/m1/s1 Copy

  
• IUPAC Standard InChIKey: UOYZRHLGPUDVGI-RWHUMPPASA-N Copy
• Chemical structure:
  This structure is also available as a 2d Mol file
• Stereoisomers:
  • 3-epi-GA1 methyl ester TMS ether
  • [13C]GA1 methyl ester TMS ether
  • 3-epi-GA1, MeTMSi
  • [2H2]GA1, MeTMS
  • [14C1]GA1 methyl ester TMS ether
  • GA3-isolactone, methyl ester TMS ether
  • [13C]3-epi-GA1 methyl ester TMS ether
  • epi-GA1, MeTMSi
• Other names: GA1, MeTMSi; GA1 methyl ester TMS ether; GA1, methyl ester TMS; Gibberelline GA1, methyl ester TMS ether; Gibberellin GA1, methyl ester trimethylsilyl ether
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Normal alkane RI, non-polar column, custom temperature program
  • References
  • Notes
• Other data available:
  • Gas Chromatography
• Options:
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Normal alkane RI, non-polar column, custom temperature program

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

References

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Suzuki, Ishiyama, et al., 2005
Suzuki, H.; Ishiyama, K.; Kobayashi, M.; Ogawa, T., Specific expression of the gibberellin 3β -hydroxylase gene, HvGA3ox2, in the epithelium is important for Amy1 expression in germinating barley seeds, Plant Biotechnology, 2005, 22, 3, 195-200, https://doi.org/10.5511/plantbiotechnology.22.195 . [all data]

Chung, Kuo, et al., 2003
Chung, J.-D.; Kuo, S.-R.; Chien, C.-T., Identification and quantification of gibberellin transformation and dosage changes in good and poor flowering clones of Calocedrus formosana grafts, Taiwan J. For. Sci., 2003, 18, 4, 387-400. [all data]

Stokes, Mander, et al., 2003
Stokes, T.S.; Mander, L.N.; Croker, S.J.; Twitchin, B.; Hanke, D.E., 3β,13-Dihydroxylated C₂₀ gibberellins from inflorescences of Rumex acetosa L., Phytochemistry, 2003, 62, 2, 165-174, https://doi.org/10.1016/S0031-9422(02)00442-9 . [all data]

Yamazaki, Nishijima, et al., 2002
Yamazaki, H.; Nishijima, T.; Koshioka, M.; Miura, H., Gibberellins do no act against abscisic acid in the regulation of bulb dormancy of Allium wakegi Araki, Plant Growth Regul., 2002, 36, 3, 223-229, https://doi.org/10.1023/A:1016577529378 . [all data]

Chang, Chen, et al., 2001
Chang, S.-T.; Chen, W.-S.; Koshioka, M.; Mander, L.N.; Huang, K.-L.; Du, B.-S., Gibberellins in relation to flowering in Polianthes tuberosa, Physiol. Plant., 2001, 112, 3, 429-432, https://doi.org/10.1034/j.1399-3054.2001.1120317.x . [all data]

Fos, Nuez, et al., 2000
Fos, M.; Nuez, F.; Garcia-Martinez, J.L., The gene pat-2, which induces natural partenocarpy, alters the gibberellin content in unpollinated tomato ovaries, Plant Physiol., 2000, 122, 2, 471-479, https://doi.org/10.1104/pp.122.2.471 . [all data]

Martínez-García, Santes, et al., 2000
Martínez-García, J.F.; Santes, C.M.; García-Martínez, J.L., The end-of-day far-red irradiation increases gibberellin A₁ content in cowpea (Vigna sinensis) epicotyls by reducing its inactivation, Physiol. Plant., 2000, 108, 4, 426-434, https://doi.org/10.1034/j.1399-3054.2000.t01-1-100413.x . [all data]

Pérez, Viani, et al., 2000
Pérez, F.J.; Viani, C.; Retamales, J., Bioactive gibberellins in seeded and seedless grapes: identification and changes in content during berry development, Am. J. Enol. Vitic, 2000, 51, 4, 315-318. [all data]

Ross, MacKenzie-Hose, et al., 1999
Ross, J.J.; MacKenzie-Hose, A.K.; Davies, P.J.; Lester, D.R.; Twitchin, B.; Reid, J.B., Further evidence for feedback regulation of gibberellin biosynthesis in pea, Physiol. Plant., 1999, 105, 3, 532-538, https://doi.org/10.1034/j.1399-3054.1999.105319.x . [all data]

Wang, Little, et al., 1996
Wang, Q.; Little, C.H.A.; Moritz, T.; Odén, P.C., Identification of endogenous gibberellins, and metabolism of tritiated and deuterated GA₄, GA₉, and GA₂₀, in Scots pine (Pinus sylvestris) shoots, Physiol. Plant., 1996, 97, 4, 764-771, https://doi.org/10.1111/j.1399-3054.1996.tb00542.x . [all data]

Kawaide, Sassa, et al., 1995
Kawaide, H.; Sassa, T.; Kamiya, Y., Plant-like biosynthesis of gibberellin A₁ in the fungus Phaeosphaeria Sp. L487, Phytochemistry, 1995, 39, 2, 305-310, https://doi.org/10.1016/0031-9422(95)00006-S . [all data]

Koshioka, Nishijama, et al., 1995
Koshioka, M.; Nishijama, T.; Mander, L.N., Gibberellin metabolism in suspension cultured cells of Raphanus Sativus, Phytochemistry, 1995, 38, 2, 359-363, https://doi.org/10.1016/0031-9422(94)00624-3 . [all data]

Lange, Hedden, et al., 1993
Lange, T.; Hedden, P.; Graebe, J.E., Biosynthesis of 12α- and 13-hydroxylated gibberellins in a cell-free system from Cucurbita maxima endosperm and the identification of new endogenous gibberellins, Planta, 1993, 189, 3, 340-349, https://doi.org/10.1007/BF00194430 . [all data]

Lange, Hedden, et al., 1993, 2
Lange, T.; Hedden, P.; Graebe, J.E., Gibberellin biosynthesis in cell-free extracts from developing Cucurbita maxima embryos and the identification of new endogenous gibberellins, Planta, 1993, 189, 3, 350-358, https://doi.org/10.1007/BF00194431 . [all data]

Nishijima, Murakami, et al., 1993
Nishijima, T.; Murakami, F.; Koshioka, M.; Yamazaki, H., Endogenous gibberellins in Aralia cordata, Japan Society for Biosci. Biotechnol. Agrochem., 1993, 57, 1, 1953-1954, https://doi.org/10.1271/bbb.57.1953 . [all data]

Talon, Zacarias, et al., 1992
Talon, M.; Zacarias, L.; PRimo-Millo, E., Gibberellins and Partenocarpic ability in developing ovaries of seedless mandarins, Plant Physiol., 1992, 99, 4, 1575-1581, https://doi.org/10.1104/pp.99.4.1575 . [all data]

Beall, Morgan, et al., 1991
Beall, F.D.; Morgan, P.W.; Mander, L.N.; Miller, F.R.; Babb, K.H., Genetic regulation of development in Sorghum bicolor. V. The ma₃^R allele results in gibberellin enrichment, Plant Physiol., 1991, 95, 1, 116-125, https://doi.org/10.1104/pp.95.1.116 . [all data]

Garcia-Martinez, Santes, et al., 1991
Garcia-Martinez, J.L.; Santes, C.; Croker, S.J.; Hedden, P., Identification, quantitation and distribution of gibberellins in fruits of Pisum sativum L. cv. Alaska during pod development, Planta, 1991, 184, 1, 53-60, https://doi.org/10.1007/BF00208236 . [all data]

Matheussen, Morgan, et al., 1991
Matheussen, A.-M.; Morgan, P.W.; Frederiksen, R.A., Implication of gibberellins in head smut (Sporisorium reilianum) of Sorghum bicolor, Plant Physiol., 1991, 96, 2, 537-544, https://doi.org/10.1104/pp.96.2.537 . [all data]

Nakayama, Yamane, et al., 1990
Nakayama, M.; Yamane, H.; Yokota, T.; Yamaguchi, I.; Murofushi, N.; Takahashi, N.; Nishijima, T.; Katsura, N.; Nonaka, M.; Gaskin, P.; MacMillan, J.; Mander, L.N.; Chu, A., Endogenous gibberellins in mature seed of Raphanus sativus L. cv. Taibyo-sobutori, Agric. Biol. Chem., 1990, 54, 3, 837-840, https://doi.org/10.1271/bbb1961.54.837 . [all data]

Yamane, Fujioka, et al., 1988
Yamane, H.; Fujioka, S.; Spray, C.R.; Phinney, B.O.; MacMillan, J.; Gaskin, P.; Takahashi, N., Endogenous Gibberellines from Sporophytes of Two Tree Ferns, Cibotium glaucum and Dicksonia antarctica, Plant Phisiol., 1988, 86, 3, 857-862, https://doi.org/10.1104/pp.86.3.857 . [all data]

Notes

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, References

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