GA19, MeTMS
- Formula: C25H38O6Si
- Molecular weight: 462.6511
- IUPAC Standard InChIKey: LITPYBGNJGOPIR-WPTBREKFSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA19 methyl ester TMS ether; Gibberelline GA19, methyl ester TMS ether; Gibberellin GA19, methyl ester trimethylsilyl ether
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Van Den Dool and Kratz RI, non-polar column, custom temperature program
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | HP-1 | HP-1 | HP-1 | DB-5 |
Column length (m) | 30. | 30. | 12. | 12. | 15. |
Carrier gas | He | He | |||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.22 | 0.22 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | |||
Program | 60C (1min) => 15C/min => 200C => 5C/min => 285C | 60C (1min) => 15C/min => 200C => 5C/min => 285C | 60C(0.5min) => 20C/min => 200C => 5C/min => 300C | 60C(0.5min) => 20C/min => 200C => 5C/min => 300C | 60C(0.5min) => 20C/min => 200C => 5C/min => 300C |
I | 2600. | 2600. | 2605. | 2606. | 2618. |
Reference | Kim, Lee, et al., 2003 | Kim, Lee, et al., 2003 | Pearce, Hutt, et al., 2002 | Pearce, Hutt, et al., 2002 | Pearce, Hutt, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | OV-1 | OV-1 | OV-1 | CP-Sil5 CB MS |
Column length (m) | 15. | 25. | 25. | 25. | 25. |
Carrier gas | He | He | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.2 | 0.2 | 0.2 | 0.25 |
Phase thickness (μm) | 0.25 | ||||
Program | 60C(0.5min) => 20C/min => 200C => 5C/min => 300C | 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) | 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) | 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) | 90C(1min) => 20C/min => 220C => 4C/min => 290C |
I | 2620. | 2596. | 2601. | 2596. | 2627. |
Reference | Pearce, Hutt, et al., 2002 | Kobayashi, MacMillan, et al., 2000 | Kobayashi, MacMillan, et al., 2000 | Davis, Kobayashi, et al., 1999 | Roberts, Blake, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP-Sil5 CB MS | DB-1 | OV-1 | BP-1 | BP-1 |
Column length (m) | 25. | 15. | 25. | 25. | 25. |
Carrier gas | He | ||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.2 | 0.2 | 0.2 |
Phase thickness (μm) | 0.33 | 0.25 | 0.1 | 0.1 | |
Program | 90C(1min) => 20C/min => 220C => 4C/min => 290C | 120(2min) => (16C/min) => 216(5min) => (8C/min) => 280C | 60C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(2min) => 10C/min => 150C => 3C/min => 300C |
I | 2629. | 2591. | 2596. | 2607. | 2607. |
Reference | Roberts, Blake, et al., 1999 | Hisamatsu, Koshioka, et al., 1998 | Webb, Appleford, et al., 1998 | Webb, Appleford, et al., 1998 | Webb, Appleford, et al., 1998 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | DB-1 | CP Sil 5 CB | CP Sil 5 CB | DB-1 |
Column length (m) | 30. | 30. | 30. | 30. | 15. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.4 | 0.4 | 0.25 | ||
Program | 40C (2min) => 10C/min => 150C => 3C/min => 300C | 40C (2min) => 10C/min => 150C => 3C/min => 300C | 200C => 25C/min => 250C => 4C/min => 280C(4min) | 200C => 25C/min => 250C => 4C/min => 280C(4min) | 80C(1min) => 30C/min => 245C => 5C/min => 300C |
I | 2597. | 2601. | 2610. | 2611. | 2598. |
Reference | Grünzweig, Rabinowitch, et al., 1997 | Grünzweig, Rabinowitch, et al., 1997 | Kappers, Jordi, et al., 1997 | Kappers, Jordi, et al., 1997 | Rijnders, Yang, et al., 1997 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-1 | OV-1 | OV-1 | OV-1 | DB-1 |
Column length (m) | 25. | 25. | 25. | 25. | 15. |
Carrier gas | He | ||||
Substrate | |||||
Column diameter (mm) | 0.2 | 0.2 | 0.2 | 0.2 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Program | 50C(2min) => 10C/min => 150C => 3C/min => 300C | 50C(2min) => 10C/min => 150C => 3C/min => 300C | 50C(2min) => 10C/min => 150C => 3C/min => 300C | 50C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(1min) => 20C/min => 200C => 4C/min => 260C |
I | 2590. | 2600. | 2602. | 2602. | 2596. |
Reference | Kobayashi, Spray, et al., 1996 | Kobayashi, Spray, et al., 1996 | Kobayashi, Spray, et al., 1996 | Kobayashi, Spray, et al., 1996 | Ridoutt, Pharis, et al., 1995 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | OV-1 | OV-1 | OV-1 | OV-1 |
Column length (m) | 15. | 25. | 25. | 25. | 25. |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.2 | 0.2 | 0.2 | 0.2 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | ||
Program | 60C(1min) => 20C/min => 200C => 4C/min => 260C | 60C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) | 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) |
I | 2599. | 2596. | 2601. | 2608. | 2608. |
Reference | Ridoutt, Pharis, et al., 1995 | Santes, Hedden, et al., 1995 | Santes, Hedden, et al., 1995 | Talo, Spray, et al., 1995 | Talo, Spray, et al., 1995 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP Sil 5 CB | CP Sil 5 CB | BP-1 | BP-1 | DB-1 |
Column length (m) | 25. | 25. | 25. | 25. | 15. |
Carrier gas | He | He | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.22 | 0.22 | 0.22 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | ||
Program | 50C(1min) => 15C/min => 220C => 2C/min => 300C | 50C(1min) => 15C/min => 220C => 2C/min => 300C | 60C => 30C/min => 240C => 3C/min => 290C | 60C => 30C/min => 240C => 3C/min => 290C | 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
I | 2627. | 2629. | 2626. | 2627. | 2608. |
Reference | Blake and Browning, 1994 | Blake and Browning, 1994 | Hasan, Ridoutt, et al., 1994 | Hasan, Ridoutt, et al., 1994 | Pearce, Koshioka, et al., 1994 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP Sil 5 CB | CP Sil 5 CB | SE-52 | SE-52 | OV-1 |
Column length (m) | 25. | 25. | 25. | 25. | 25. |
Carrier gas | He | He | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.22 | 0.22 | 0.22 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | ||
Program | 60C(0.3min) => 20C/min => 220C => 4C/min => 300C | 60C(0.3min) => 20C/min => 220C => 4C/min => 300C | 50C => 15C/min => 240C => 4C/min => 300C | 50C => 15C/min => 240C => 4C/min => 300C | 60C(2min) => 10C/min => 150C => 3C/min => 310C |
I | 2627. | 2629. | 2590. | 2591. | 2595. |
Reference | Taylor, Blake, et al., 1994 | Taylor, Blake, et al., 1994 | Hedden, Hoad, et al., 1993 | Hedden, Hoad, et al., 1993 | Waycott, Smith, et al., 1991 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|
Active phase | SPB-1 | SPB-1 | OV-1 | OV-1 |
Column length (m) | 30. | 30. | 25. | |
Carrier gas | He | He | He | He |
Substrate | ||||
Column diameter (mm) | 0.25 | 0.25 | 0.2 | |
Phase thickness (μm) | 0.25 | 0.25 | ||
Program | 60C(2min) => 20C/min => 160C => 5C/min => 290C | 60C(2min) => 20C/min => 160C => 5C/min => 290C | 50C(1min) => 15C/min => 200C => 4C/min => 260C | 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) |
I | 2614. | 2616. | 2590. | 2594. |
Reference | Poling and Maier, 1988 | Poling and Maier, 1988 | Heupel R.C., Phinney B.O., et al., 1985 | Gaskin, Gilmour, et al., 1984 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kim, Lee, et al., 2003
Kim, S.-K.; Lee, S.-C.; Shin, D.-H.; Jang, S.-W.; Nam, J.-W.; Park, T.-S.; Lee, I.-J.,
Quantification of endogenous gibberellins in leaves and tubers of Chinese yam, Dioscorea opposita Thunb. cv. Tsukune during tuber enlargement,
Plant Growth Regul., 2003, 39, 2, 125-130, https://doi.org/10.1023/A:1022569506883
. [all data]
Pearce, Hutt, et al., 2002
Pearce, D.W.; Hutt, O.E.; Rood, S.B.; Mander, L.N.,
Gibberellins in shoots and developing capsules of Populus species,
Phytochemistry, 2002, 59, 6, 679-687, https://doi.org/10.1016/S0031-9422(02)00009-2
. [all data]
Kobayashi, MacMillan, et al., 2000
Kobayashi, M.; MacMillan, J.; Phinney, B.; Gaskin, P.; Spray, C.R.; Hedden, P.,
Gibberellin biosynthesis: metabolic evidence for three steps in the early 13-hydroxylation pathway of rice,
Phytochemistry, 2000, 55, 4, 317-321, https://doi.org/10.1016/S0031-9422(00)00265-X
. [all data]
Davis, Kobayashi, et al., 1999
Davis, G.; Kobayashi, M.; Phinney, B.O.; Lange, T.; Croker, S.J.; Gaskin, P.; MacMillan, J.,
Gibberellin biosynthesis in maize. Metabolic studies with GA15, GA24, GA25, GA7, and 2,3-dehydro-GA9,
Plant Physiol., 1999, 121, 3, 1037-1045, https://doi.org/10.1104/pp.121.3.1037
. [all data]
Roberts, Blake, et al., 1999
Roberts, A.V.; Blake, P.S.; Lewis, R.; Taylor, J.M.; Dunstan, D.I.,
The effect of gibberellins on flowering in roses,
J. Plant Growth Regul., 1999, 18, 3, 113-119, https://doi.org/10.1007/PL00007058
. [all data]
Hisamatsu, Koshioka, et al., 1998
Hisamatsu, T.; Koshioka, M.; Kubota, S.; Nishijima, T.; Yamane, H.; King, R.W.; Mander, L.N.,
Isolation and identification of GA112 (12β-hydroxy-GA12) in Matthiola incana,
Phytochemistry, 1998, 47, 1, 3-6, https://doi.org/10.1016/S0031-9422(97)00543-8
. [all data]
Webb, Appleford, et al., 1998
Webb, S.E.; Appleford, N.E.J.; Gaskin, P.; Lenton, J.R.,
Gibberellins in internodes and ears of wheat containing different dwarfing alleles,
Phytochemistry, 1998, 47, 5, 671-677, https://doi.org/10.1016/S0031-9422(97)00684-5
. [all data]
Grünzweig, Rabinowitch, et al., 1997
Grünzweig, J.M.; Rabinowitch, H.D.; Katan, J.; Wodner, M.; Ben-Tal, Y.,
Endogenous gibberellins in foliage of tomato (Lycopersicon esculentum),
Phytochemistry, 1997, 46, 5, 811-815, https://doi.org/10.1016/S0031-9422(97)00383-X
. [all data]
Kappers, Jordi, et al., 1997
Kappers, I.F.; Jordi, W.; Maas, F.M.; van der Plas, L.H.W.,
Gibberellins in leaves of Alstroemeria hybrida: identification and quantification in relation to leaf age,
J. Plant Growth Regul., 1997, 16, 4, 219-225, https://doi.org/10.1007/PL00007000
. [all data]
Rijnders, Yang, et al., 1997
Rijnders, J.G.H.M.; Yang, Y.-Y.; Kamiya, Y.; Takahashi, N.; Barendse, G.W.M.; Blom, C.W.P.M.; Voesenek, L.A.C.J.,
Ethylene enhances gibberellin levels and petiole sensitivity in flooding-tolerant Rumex palustris but not in flooding-intolerant R. acetosa,
Planta, 1997, 203, 1, 20-25, https://doi.org/10.1007/s00050160
. [all data]
Kobayashi, Spray, et al., 1996
Kobayashi, M.; Spray, C.R.; Phinney, B.O.; Gaskin, P.; MacMillan, J.,
Gibberellin metabolism in maize. The stepwise conversion of gibberellin A12-aldehyde to gibberellin A20,
Plant Physiol., 1996, 110, 413-418. [all data]
Ridoutt, Pharis, et al., 1995
Ridoutt, B.G.; Pharis, R.P.; Sands, R.,
Identification and quantification of cambial region hormones of Eucalyptus globulus,
Plant Cell Physiol., 1995, 36, 6, 1143-1147. [all data]
Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L.,
Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set,
Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T
. [all data]
Talo, Spray, et al., 1995
Talo, A.; Spray, C.R.; Somers, D.A.; Donovan, C.M.; Gaskin, P.; Macmillian, J.; Phinney, B.O.,
Endogenous gibberellins from callus cultures of maize,
Phytochemistry, 1995, 40, 1, 11-15, https://doi.org/10.1016/0031-9422(95)00000-W
. [all data]
Blake and Browning, 1994
Blake, P.S.; Browning, G.,
Gibberellins in developing fruits of Prunus avium,
Phytochemistry, 1994, 35, 6, 1383-1386, https://doi.org/10.1016/S0031-9422(00)86860-0
. [all data]
Hasan, Ridoutt, et al., 1994
Hasan, O.; Ridoutt, B.G.; Ross, J.J.; Davies, N.W.; Reid, J.B.,
Identification and quantification of endogenous gibberellins in apical buds and the cambial region of Eucalyptus,
Physiol. Plant., 1994, 90, 3, 475-480, https://doi.org/10.1111/j.1399-3054.1994.tb08804.x
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Taylor, Blake, et al., 1994
Taylor, D.R.; Blake, P.S.; Browning, G.,
Identification of gibberellins in leaf tissues of strawberry (Fragaria × ananassa Duch.) grown under different photoperiods,
Plant Growth Regul., 1994, 15, 3, 235-240, https://doi.org/10.1007/BF00029896
. [all data]
Hedden, Hoad, et al., 1993
Hedden, P.; Hoad, G.V.; Gaskin, P.; Lewis, M.J.; Green, J.R.; Furber, M.; Mander, L.N.,
Kaurenoids and gibberellins, including the newly characterized gibberellin A88, in developing apple seeds,
Phytochemistry, 1993, 32, 2, 231-237, https://doi.org/10.1016/S0031-9422(00)94973-2
. [all data]
Waycott, Smith, et al., 1991
Waycott, W.; Smith, V.A.; Gaskin, P.; MacMillan, J.; Taiz, L.,
The endogenous gibberellins of dwarf mutants of lettuce,
Plant Physiol., 1991, 95, 4, 1169-1173, https://doi.org/10.1104/pp.95.4.1169
. [all data]
Poling and Maier, 1988
Poling, S.M.; Maier, V.P.,
Identification of endogenous gibberellins in navel orange shoots,
Plant Physiol., 1988, 88, 3, 639-642, https://doi.org/10.1104/pp.88.3.639
. [all data]
Heupel R.C., Phinney B.O., et al., 1985
Heupel R.C.; Phinney B.O.; Spray C.R.; Gaskin P.; MacMillan J.; Hedden P.; Graebe J.E.,
Native gibberellins and the metabolism of [14C] gibberellin A53 and of [17-C-13,17-3H)] gibberellin A-20 in tassels of Zea-mays,
Phytochemistry, 1985, 24, 1, 47-53, https://doi.org/10.1016/S0031-9422(00)80805-5
. [all data]
Gaskin, Gilmour, et al., 1984
Gaskin, P.; Gilmour, S.J.; Lenton, J.R.; MacMillan, J.; Sponsel, V.M.,
Endogenous gibberellins and kauranoids identified from developing and germinating barley grain,
J. Plant Growth Regul., 1984, 2, 1-4, 229-242, https://doi.org/10.1007/BF02042252
. [all data]
Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, References
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