GA17, MeTMS
- Formula: C26H40O7Si
- Molecular weight: 492.6771
- IUPAC Standard InChIKey: JZPIBPZKAPRUHC-IWOBXAFHSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA17 methyl ester TMS ether; Gibberelline GA17, methyl ester TMS ether; GA17, methyl ester TMS
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Normal alkane RI, non-polar column, custom temperature program
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | BP-1 | DB-1 | BP-1 | Ultra 2 |
Column length (m) | 30. | 25. | 15. | 25. | 22. |
Carrier gas | He | He | Helium | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.2 | 0.25 | 0.25 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.33 | 0.52 |
Program | 60C (2min) => 2C/min => 210C => 2C/min => 280C(5min) | 60C (1min) => 20C/min => 240C => 4C/min => 300C | not specified | 60C(1min) => 20C/min => 240C => 4C/min => 300C | not specified |
I | 2585. | 2582. | 2573. | 2609. | 2557. |
Reference | Nakayama, Koshioka, et al., 2001 | Pérez, Viani, et al., 2000 | Motosugi, Nishijima, et al., 1996 | Lange, Hedden, et al., 1993 | Talon, Zacarias, et al., 1992 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | Methyl Silicone | Methyl Silicone | Ultra-2 | DB-1 |
Column length (m) | 12. | 25. | 15. | ||
Carrier gas | He | Helium | |||
Substrate | |||||
Column diameter (mm) | 0.2 | 0.32 | 0.258 | ||
Phase thickness (μm) | 0.33 | 0.52 | |||
Program | 60C(1min) => 15C/min => 200C => 5C/min => 270C | not specified | not specified | 50C => 40C/min => 220C => 8C/min => 280C | not specified |
I | 2581. | 2592. | 2594. | 2556. | 2572. |
Reference | Beall, Morgan, et al., 1991 | Garcia-Martinez, Santes, et al., 1991 | Garcia-Martinez, Santes, et al., 1991 | Talon, Zeevaart, et al., 1991 | Nakayama, Yamane, et al., 1990 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nakayama, Koshioka, et al., 2001
Nakayama, M.; Koshioka, M.; Matsui, H.; Ohara, H.; Mander, L.N.; Leitch, S.K.; Twitchin, B.; Kraft-Klaunzer, P.; Pharis, R.P.; Yokota, T.,
Endogenous gibberellins in immature seeds of Prunus persica L.: identification of GA118, GA119, GA120, GA121, GA122 and GA126,
Phytochemistry, 2001, 57, 5, 749-758, https://doi.org/10.1016/S0031-9422(01)00154-6
. [all data]
Pérez, Viani, et al., 2000
Pérez, F.J.; Viani, C.; Retamales, J.,
Bioactive gibberellins in seeded and seedless grapes: identification and changes in content during berry development,
Am. J. Enol. Vitic, 2000, 51, 4, 315-318. [all data]
Motosugi, Nishijima, et al., 1996
Motosugi, H.; Nishijima, T.; Hiehata, N.; Koshioka, M.; Sugiura, A.,
Endogenous gibberellins in the xylem exudate from apple trees,
Biosci. Biotechnol. Biochem., 1996, 60, 9, 1500-1502, https://doi.org/10.1271/bbb.60.1500
. [all data]
Lange, Hedden, et al., 1993
Lange, T.; Hedden, P.; Graebe, J.E.,
Gibberellin biosynthesis in cell-free extracts from developing Cucurbita maxima embryos and the identification of new endogenous gibberellins,
Planta, 1993, 189, 3, 350-358, https://doi.org/10.1007/BF00194431
. [all data]
Talon, Zacarias, et al., 1992
Talon, M.; Zacarias, L.; PRimo-Millo, E.,
Gibberellins and Partenocarpic ability in developing ovaries of seedless mandarins,
Plant Physiol., 1992, 99, 4, 1575-1581, https://doi.org/10.1104/pp.99.4.1575
. [all data]
Beall, Morgan, et al., 1991
Beall, F.D.; Morgan, P.W.; Mander, L.N.; Miller, F.R.; Babb, K.H.,
Genetic regulation of development in Sorghum bicolor. V. The ma3R allele results in gibberellin enrichment,
Plant Physiol., 1991, 95, 1, 116-125, https://doi.org/10.1104/pp.95.1.116
. [all data]
Garcia-Martinez, Santes, et al., 1991
Garcia-Martinez, J.L.; Santes, C.; Croker, S.J.; Hedden, P.,
Identification, quantitation and distribution of gibberellins in fruits of Pisum sativum L. cv. Alaska during pod development,
Planta, 1991, 184, 1, 53-60, https://doi.org/10.1007/BF00208236
. [all data]
Talon, Zeevaart, et al., 1991
Talon, M.; Zeevaart, J.A.D.; Gage, D.A.,
Identification of gibberellins in spinach and effects of light and darkness on their levels,
Plant Physiol., 1991, 97, 4, 1521-1526, https://doi.org/10.1104/pp.97.4.1521
. [all data]
Nakayama, Yamane, et al., 1990
Nakayama, M.; Yamane, H.; Yokota, T.; Yamaguchi, I.; Murofushi, N.; Takahashi, N.; Nishijima, T.; Katsura, N.; Nonaka, M.; Gaskin, P.; MacMillan, J.; Mander, L.N.; Chu, A.,
Endogenous gibberellins in mature seed of Raphanus sativus L. cv. Taibyo-sobutori,
Agric. Biol. Chem., 1990, 54, 3, 837-840, https://doi.org/10.1271/bbb1961.54.837
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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