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5«alpha»-Androstan-3,17-dione, TMS


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-5MS2660.Parr, Zapp, et al., 200716.5 m/0.25 mm/0.25 «mu»m, He, 20. K/min, 320. C @ 2. min; Tstart: 140. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-12645.Bowers and Borts, 199630. m/0.25 mm/0.1 «mu»m, He; Program: 170C => 20C/min => 260C => 2.7C/min => 305C => 20C/min => 320C
CapillaryBPX-52649.Bowers and Borts, 199630. m/0.22 mm/0.25 «mu»m, He; Program: 170C => 20C/min => 260C => 2.7C/min => 305C => 20C/min => 320C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Parr, Zapp, et al., 2007
Parr, M.K.; Zapp, J.; Becker, M.; Opfermann, G.; Bartz, U.; Schanzer, W., Steroidal isomers with uniform mass spectra of their per-TMS derivatives: Synthesis of 17-hydroxyandrostan-3-ones, androst-1-, and -4-ene-3,17-diols, Steroids, 2007, 72, 6-7, 545-551, https://doi.org/10.1016/j.steroids.2007.03.006 . [all data]

Bowers and Borts, 1996
Bowers, L.D.; Borts, D.J., Separation and confirmation of anabolic steroids with quadrupole ion trap tandem mass spectrometry, J. Chromatogr. B, 1996, 687, 1, 69-78, https://doi.org/10.1016/S0378-4347(96)00231-9 . [all data]


Notes

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