12α-hydroxy-GA37 methyl ester TMS ether
- Formula: C27H44O6Si2
- Molecular weight: 520.8057
- IUPAC Standard InChI: InChI=1S/C27H44O6Si2/c1-16-13-27-14-17(16)18(32-34(4,5)6)12-19(27)26-11-10-20(33-35(7,8)9)25(2,24(29)31-15-26)22(26)21(27)23(28)30-3/h17-22H,1,10-15H2,2-9H3/t17?,18-,19-,20-,21+,22+,25+,26+,27-/m1/s1
- IUPAC Standard InChIKey: OARUYXYOZCIIMC-OGZOHQNYSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: 12-α-Hydroxy-GA37, methyl ester, TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2953. | Gaskin, Hutchison, et al., 1984 | Program: not specified |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2977. | Lange, Hedden, et al., 1993 | 25. m/0.32 mm/0.33 μm, He; Program: 50C(1min) => 20C/min => 240C => 4C/min => 295C |
| Capillary | BP-1 | 2991. | Lange, Hedden, et al., 1993, 2 | 25. m/0.25 mm/0.33 μm, He; Program: 60C(1min) => 20C/min => 240C => 4C/min => 300C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Gaskin, Hutchison, et al., 1984
Gaskin, P.; Hutchison, M.; Lewis, N.; MacMillan, J.; Phinney, B.O.,
Microbiological conversion of 12-oxygenated and other derivatives of ent-kaur-16-en-19-oic acid by Gibberella Fujikuroi, mutant B1-41a,
Phytochemistry, 1984, 23, 3, 559-564, https://doi.org/10.1016/S0031-9422(00)80380-5
. [all data]
Lange, Hedden, et al., 1993
Lange, T.; Hedden, P.; Graebe, J.E.,
Biosynthesis of 12α- and 13-hydroxylated gibberellins in a cell-free system from Cucurbita maxima endosperm and the identification of new endogenous gibberellins,
Planta, 1993, 189, 3, 340-349, https://doi.org/10.1007/BF00194430
. [all data]
Lange, Hedden, et al., 1993, 2
Lange, T.; Hedden, P.; Graebe, J.E.,
Gibberellin biosynthesis in cell-free extracts from developing Cucurbita maxima embryos and the identification of new endogenous gibberellins,
Planta, 1993, 189, 3, 350-358, https://doi.org/10.1007/BF00194431
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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