[14C1]GA4 methyl ester TMS ether
- Formula: C23H34O5Si
- Molecular weight: 418.5986
- IUPAC Standard InChI: InChI=1S/C23H34O5Si/c1-13-11-22-12-14(13)7-8-15(22)23-10-9-16(28-29(4,5)6)21(2,20(25)27-23)18(23)17(22)19(24)26-3/h14-18H,1,7-12H2,2-6H3/t14?,15-,16+,17-,18-,21-,22+,23-/m0/s1
- IUPAC Standard InChIKey: ATWIBZVZMYFKOI-DTOPKNIOSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: [2H2]GA4 methyl ester TMS ether; [13C] GA4 methyl ester TMS ether; [13C]endo-GA4 methyl ester TMS ether; endo-GA4 methyl ester TMS ether; [2H2] GA4 MeTMSi
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Van Den Dool and Kratz RI, non-polar column, custom temperature program
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | BP-1 | BP-1 | OV-1 | OV-1 | OV-1 |
| Column length (m) | 25. | 25. | 25. | 25. | 25. |
| Carrier gas | He | He | |||
| Substrate | |||||
| Column diameter (mm) | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Phase thickness (μm) | 0.1 | 0.1 | 0.25 | 0.25 | 0.25 |
| Program | 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) | 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) | 50C(2min) => 10C/min => 150C => 3C/min => 300C | 50C(2min) => 10C/min => 150C => 3C/min => 300C | 50C(2min) => 10C/min => 150C => 3C/min => 300C |
| I | 2498. | 2498. | 2511. | 2481. | 2478. |
| Reference | MacMillan, Ward, et al., 1997 | MacMillan, Ward, et al., 1997 | Kobayashi, Gaskin, et al., 1993 | Kobayashi, Gaskin, et al., 1993 | Kobayashi, Gaskin, et al., 1993 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
MacMillan, Ward, et al., 1997
MacMillan, J.; Ward, D.A.; Phillips, A.L.; Sánchez-Beltrán, M.J.; Gaskin, P.; Lange, T.; Hedden, P.,
Gibberellin biosynthesis from gibberellin A12-aldehyde in endosperm and embryos of Marah macrocarpus,
Plant Physiol., 1997, 113, 4, 1369-1377, https://doi.org/10.1104/pp.113.4.1369
. [all data]
Kobayashi, Gaskin, et al., 1993
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Suzuki, Y.; Phinney, B.O.; MacMillan, J.,
Metabolism and biological activity of Gibberellin A4 in vegetative shoots of Zea mays, Oryza sativa, and Arabidopsis thaliana,
Plant Physiol., 1993, 102, 379-386. [all data]
Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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