[14C1]GA4 methyl ester TMS ether
- Formula: C23H34O5Si
- Molecular weight: 418.5986
- IUPAC Standard InChI: InChI=1S/C23H34O5Si/c1-13-11-22-12-14(13)7-8-15(22)23-10-9-16(28-29(4,5)6)21(2,20(25)27-23)18(23)17(22)19(24)26-3/h14-18H,1,7-12H2,2-6H3/t14?,15-,16+,17-,18-,21-,22+,23-/m0/s1
- IUPAC Standard InChIKey: ATWIBZVZMYFKOI-DTOPKNIOSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: [2H2]GA4 methyl ester TMS ether; [13C] GA4 methyl ester TMS ether; [13C]endo-GA4 methyl ester TMS ether; endo-GA4 methyl ester TMS ether; [2H2] GA4 MeTMSi
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-30 | 2521. | Odén, Wang, et al., 1995 | 25. m/0.25 mm/0.25 μm; Program: 80C(1min) => (20C/min) => 200C => (4C/min) => 250C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | BP-1 | 2498. | MacMillan, Ward, et al., 1997 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | BP-1 | 2498. | MacMillan, Ward, et al., 1997 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | OV-1 | 2511. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2481. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2478. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-30 | 2515. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2517. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2517. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2517. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2517. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2518. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Odén, Wang, et al., 1995
Odén, P.C.; Wang, Q.; Högberg, K.-A.; Werner, M.,
Transport and metabolism of gibberellins in relation to flower bud differentiation in Norway spruce (Picea abies),
Tree Physiol., 1995, 15, 7-8, 451-456, https://doi.org/10.1093/treephys/15.7-8.451
. [all data]
MacMillan, Ward, et al., 1997
MacMillan, J.; Ward, D.A.; Phillips, A.L.; Sánchez-Beltrán, M.J.; Gaskin, P.; Lange, T.; Hedden, P.,
Gibberellin biosynthesis from gibberellin A12-aldehyde in endosperm and embryos of Marah macrocarpus,
Plant Physiol., 1997, 113, 4, 1369-1377, https://doi.org/10.1104/pp.113.4.1369
. [all data]
Kobayashi, Gaskin, et al., 1993
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Suzuki, Y.; Phinney, B.O.; MacMillan, J.,
Metabolism and biological activity of Gibberellin A4 in vegetative shoots of Zea mays, Oryza sativa, and Arabidopsis thaliana,
Plant Physiol., 1993, 102, 379-386. [all data]
Wang, Little, et al., 1996
Wang, Q.; Little, C.H.A.; Moritz, T.; Odén, P.C.,
Identification of endogenous gibberellins, and metabolism of tritiated and deuterated GA4, GA9, and GA20, in Scots pine (Pinus sylvestris) shoots,
Physiol. Plant., 1996, 97, 4, 764-771, https://doi.org/10.1111/j.1399-3054.1996.tb00542.x
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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