17-OH-GA53, MeTMS
- Formula: C28H48O6Si2
- Molecular weight: 536.8481
- IUPAC Standard InChI: InChI=1S/C28H48O6Si2/c1-25-13-11-14-26(2,24(30)32-4)22(25)21(23(29)31-3)27-16-19(17-33-35(5,6)7)28(18-27,15-12-20(25)27)34-36(8,9)10/h17,20-22H,11-16,18H2,1-10H3/b19-17+/t20-,21+,22-,25-,26+,27-,28-/m1/s1
- IUPAC Standard InChIKey: ULHRGZFJCAXDNX-KEQUQHISSA-N
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: GA53, 17-hydroxy, Me-TMS; 17-OH-GA53 methyl ester TMS ether
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Ultra-2 | 2708. | Talon M., Koornneef M., et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
| Capillary | Ultra-2 | 2708. | Talon, Koornneef, et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
| Capillary | Ultra-2 | 2709. | Talon, Koornneef, et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
| Capillary | Ultra-2 | 2709. | Talon, Koornneef, et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Ultra 2 | 2707. | Talon, Zacarias, et al., 1992 | 22. m/0.32 mm/0.52 μm, Helium; Program: not specified |
| Capillary | Ultra-2 | 2707. | Talon, Zeevaart, et al., 1991 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 8C/min => 280C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Talon M., Koornneef M., et al., 1990
Talon M.; Koornneef M.; Zeevaart J.A.D.,
Accumulation of C19-gibberelins in the gibbrellin-insensitive dwarf mutant gai if Arabidopsis thaliana (L.) Heynh,
Planta, 1990, 182, 4, 501-505, https://doi.org/10.1007/BF02341024
. [all data]
Talon, Koornneef, et al., 1990
Talon, M.; Koornneef, M.; Zeevaart, J.A.D.,
Endogenous gibberellins in Arabidopsis thaliana and possible steps blocked in the biosynthetic pathways of the semidwarf ga4 and ga5 mutants,
Proc. Nat. Acad. Sci. U.S.A., 1990, 87, 20, 7983-7987, https://doi.org/10.1073/pnas.87.20.7983
. [all data]
Talon, Zacarias, et al., 1992
Talon, M.; Zacarias, L.; PRimo-Millo, E.,
Gibberellins and Partenocarpic ability in developing ovaries of seedless mandarins,
Plant Physiol., 1992, 99, 4, 1575-1581, https://doi.org/10.1104/pp.99.4.1575
. [all data]
Talon, Zeevaart, et al., 1991
Talon, M.; Zeevaart, J.A.D.; Gage, D.A.,
Identification of gibberellins in spinach and effects of light and darkness on their levels,
Plant Physiol., 1991, 97, 4, 1521-1526, https://doi.org/10.1104/pp.97.4.1521
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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