Benzoic acid, 3-methyl-, methyl ester

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
386.20.036Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
60.3 ± 0.2296.CMaksimuk, Kabo, et al., 1998AC
54.8374.AStephenson and Malanowski, 1987Based on data from 359. to 500. K.; AC
53.5388.N/AMurogova, Tudorovskaya, et al., 1974AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
17.14270.6ACBlokhin, Paulechka, et al., 2002Based on data from 5. to 320. K.; AC
21.15269.9ACMaksimuk, Kabo, et al., 1998AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Maksimuk, Kabo, et al., 1998
Maksimuk, Yury V.; Kabo, Gennady J.; Simirsky, Vladimir V.; Kozyro, Alexander A.; Sevruk, Victor M., Standard Enthalpies of Formation of Some Methyl Esters of Benzene Carboxylic Acids, J. Chem. Eng. Data, 1998, 43, 3, 293-298, https://doi.org/10.1021/je970116j . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Murogova, Tudorovskaya, et al., 1974
Murogova, R.A.; Tudorovskaya, G.L.; Laufer, V.V.; Koxlova, V.D.; Seraphimov, L.A., Zh. Prikl. Khim. (S.-Peterburg), 1974, 47, 2024. [all data]

Blokhin, Paulechka, et al., 2002
Blokhin, A.V.; Paulechka, Y.U.; Kabo, G.J.; Kozyro, A.A., Thermodynamic properties of methyl esters of benzoic and toluic acids in the condensed state, The Journal of Chemical Thermodynamics, 2002, 34, 1, 29-55, https://doi.org/10.1006/jcht.2001.0852 . [all data]


Notes

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