Sparteine
- Formula: C15H26N2
- Molecular weight: 234.3803
- IUPAC Standard InChI: InChI=1S/C15H26N2/c1-3-7-16-11-13-9-12(14(16)5-1)10-17-8-4-2-6-15(13)17/h12-15H,1-11H2/t12-,13+,14+,15-
- IUPAC Standard InChIKey: SLRCCWJSBJZJBV-PYHGIMPFSA-N
- CAS Registry Number: 90-39-1
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: 7,14-Methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocine, dodecahydro-, [7S-(7α,7aα,14α,14aβ)]-; (-)-Sparteine; L-sparteine; Lupinidin; Lupinidine; Spartein; 6β,7α,9α,11α-Pachycarpine; 7,14-Methano-2H,6H-dipyrido(1,2-a:1',2'-e)(1,5)diazocine, dodecahydro-; Dodecahydro [7S-(7α,7aα,14α,14aβ)]-7,14-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocine; Sparteinum
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- Other data available:
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Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 | DB-1 | OV-1 | DB-1 | DB-1 |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | He | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.32 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.25 | |||
| Tstart (C) | 180. | 120. | 70. | 150. | 150. |
| Tend (C) | 300. | 320. | 300. | 300. | 300. |
| Heat rate (K/min) | 5. | 6. | 6. | 6. | 6. |
| Initial hold (min) | 2. | 3. | |||
| Final hold (min) | 10. | ||||
| I | 1785. | 1773. | 1777. | 1780. | 1785. |
| Reference | Przybylak, Ciesiolka, et al., 2005 | Kite and Pennington, 2003 | Woldemichael and Wink, 2002 | Greinwald, Henrichs, et al., 1995 | Kirch, Veit, et al., 1995 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Packed |
|---|---|---|---|---|---|
| Active phase | DB-1 | DB-1 | DB-1 | SE-30 | OV-1 |
| Column length (m) | 30. | 30. | 30. | 15. | 2. |
| Carrier gas | He | Helium | He | ||
| Substrate | Gas Chrom P | ||||
| Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.26 | |
| Phase thickness (μm) | 1.0 | ||||
| Tstart (C) | 150. | 150. | 150. | 150. | 120. |
| Tend (C) | 300. | 300. | 300. | 270. | 200. |
| Heat rate (K/min) | 6. | 6. | 10. | 6. | 2.5 |
| Initial hold (min) | 1. | ||||
| Final hold (min) | |||||
| I | 1780. | 1785. | 1785. | 1790. | 1810. |
| Reference | van Wyk, Greinwald, et al., 1995 | Greinwald, Canto, et al., 1992 | Wink and Witte, 1991 | Wink, Witte, et al., 1983 | Marozzi, Gambaro, et al., 1982 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary |
|---|---|
| Active phase | SE-30 |
| Column length (m) | 15. |
| Carrier gas | He |
| Substrate | |
| Column diameter (mm) | 0.26 |
| Phase thickness (μm) | |
| Tstart (C) | 150. |
| Tend (C) | 270. |
| Heat rate (K/min) | 6. |
| Initial hold (min) | |
| Final hold (min) | |
| I | 1790. |
| Reference | Wink, Witte, et al., 1981 |
| Comment | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Przybylak, Ciesiolka, et al., 2005
Przybylak, J.K.; Ciesiolka, D.; Wysocka, W.; García-López, P.M.; Ruiz-López, M.A.; Wysocki, W.; Gulewicz, K.,
Alkaloid profiles of Mexican wild lupin and an effect of alkaloid preparation from Lupinus exaltatus seeds on growth and yield of paprika (Capsicum annuum L.),
Ind. Crops Prod., 2005, 21, 1, 1-7, https://doi.org/10.1016/j.indcrop.2003.12.001
. [all data]
Kite and Pennington, 2003
Kite, G.C.; Pennington, R.T.,
Quinolizidine alkaloid status of Styphnolobium and Cladrastis (Leguminosae),
Biochem. Syst. Ecol., 2003, 31, 12, 1409-1416, https://doi.org/10.1016/S0305-1978(03)00118-2
. [all data]
Woldemichael and Wink, 2002
Woldemichael, G.M.; Wink, M.,
Concomitant occurrence of pyrrolizidine and quinolizidine alkaloids in hemiparasite Osyris alba L. (Santalaceae),
Biochem. Syst. Ecol., 2002, 30, 2, 139-149, https://doi.org/10.1016/S0305-1978(01)00065-5
. [all data]
Greinwald, Henrichs, et al., 1995
Greinwald, R.; Henrichs, C.; Veen, G.; Ross, J.H.; Witte, L.; Czygan, F.-C.,
A survey of alkaloids in templetonia biloba (Benth.) Polhill (Fabaceae: Brongniartieae),
Biochem. Syst. Ecol., 1995, 23, 6, 649-654, https://doi.org/10.1016/0305-1978(95)00035-6
. [all data]
Kirch, Veit, et al., 1995
Kirch, J.; Veit, M.; Wätzig, Greinwald; Czygan, F.-C.,
Alkaloidal variation in Genista Iobelii s.l. (Fabaceae),
Biochem. Syst. Ecol., 1995, 23, 6, 635-643, https://doi.org/10.1016/0305-1978(95)00037-2
. [all data]
van Wyk, Greinwald, et al., 1995
van Wyk, B.-E.; Greinwald, R.; Witte, L.,
Alkaloid variation in the Lupinus pusillus group (Fabaceae: tribe Genisteae),
Biochem. Syst. Ecol., 1995, 23, 5, 533-537, https://doi.org/10.1016/0305-1978(95)00036-T
. [all data]
Greinwald, Canto, et al., 1992
Greinwald, R.; Canto, P.; Bachmann, P.; Witte, L.; Czygan, F.-C.,
Distribution and taxdonomic significance of alkaloids in the Genista cinerea agregat,
Biochem. Syst. Ecol., 1992, 20, 1, 75-81, https://doi.org/10.1016/0305-1978(92)90074-N
. [all data]
Wink and Witte, 1991
Wink, M.; Witte, L.,
Storage of quinolizidine alkaloids in Macrosiphum albifrons and Aphis genistae (Homoptera: Aphididae),
Entomol. Gener., 1991, 15, 4, 237-254, https://doi.org/10.1127/entom.gen/15/1991/237
. [all data]
Wink, Witte, et al., 1983
Wink, M.; Witte, L.; Hartmann, T.; Theuring, C.; Volz. V.,
Accumulation of quinolizidine alkaloids in plants and cell suspension cultures: genera lupinus, cytisus, baptisia, genista, laburnum, and sophora,
Planta Medica, 1983, 48, 4, 253-257, https://doi.org/10.1055/s-2007-969928
. [all data]
Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F.,
Use of the retention index in gas chromatographic studies of drugs,
J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185
. [all data]
Wink, Witte, et al., 1981
Wink, M.; Witte, L.; Hartmann. T.,
Quinolizidine Alkaloid Composition of Plants and of Photomixotrophis Cell Suspension Cultures of Sarothamnus scoparius and Orobanche rapum-genistae,
Planta Medica, 1981, 43, 12, 342-352, https://doi.org/10.1055/s-2007-971522
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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