4-Heptene-3-thione,6,6,7,7-tetrafluoro-5-hydroxy-2,2-dimethyl-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

4-Heptene-3-thione,6,6,7,7-tetrafluoro-5-hydroxy-2,2-dimethyl- = 4-Hepten-3-one, 1,1,2,2-tetrafluoro-5-mercapto-6,6-dimethyl-

By formula: C9H12F4OS = C9H12F4OS

Quantity Value Units Method Reference Comment
Δr1.kcal/molEqkGindin, Nikol'skii, et al., 1983liquid phase; solvent: CS2/CH2Cl2; At -70°C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gindin, Nikol'skii, et al., 1983
Gindin, V.A.; Nikol'skii, A.L.; Ershov, B.A.; Kol'tsov, A.I.; Pashkevich, K.I., Thermodynamic and kinetic characteristics of the enol-enethiol equilibrium of polyfluorinated β-thioxo ketones based on proton NMR spectroscopic data, Zh. Org. Khim., 1983, 19, 2039-2043. [all data]


Notes

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