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Benzene, 1,1'-(diazomethylene)bis-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: H.Y. Afeefy, J.F. Liebman, and S.E. Stein

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Individual Reactions

Benzene, 1,1'-(diazomethylene)bis- = Methylene, diphenyl- + Nitrogen

By formula: C13H10N2 = C13H10 + N2

Quantity Value Units Method Reference Comment
Deltar0.0 ± 7.1kJ/molCmSimon and Peters, 1983liquid phase; solvent: Benzene; Corrected by authors in 1988

Oxygen + Benzene, 1,1'-(diazomethylene)bis- = Nitrogen + Oxonium, (diphenylmethylene)hydroxy-, hydroxide, inner salt

By formula: O2 + C13H10N2 = N2 + C13H10O2

Quantity Value Units Method Reference Comment
Deltar-201. ± 3.kJ/molCphaHartstock, Kanabus-Kaminska, et al., 1989liquid phase

Ethanol + Benzene, 1,1'-(diazomethylene)bis- = C13H28O4 + Nitrogen

By formula: C2H6O + C13H10N2 = C13H28O4 + N2

Quantity Value Units Method Reference Comment
Deltar-224. ± 4.2kJ/molCphaHartstock, Kanabus-Kaminska, et al., 1989liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Simon and Peters, 1983
Simon, J.D.; Peters, K.S., Determination of the heat of reaction for the formation of diphenylcarbene from diphenyldiazomethane using photoacoustic calorimetry, J. Am. Chem. Soc., 1983, 105, 5156-5158. [all data]

Hartstock, Kanabus-Kaminska, et al., 1989
Hartstock, F.W.; Kanabus-Kaminska, J.M.; Griller, D., Heat of formation of benzophenone oxide [1], Int. J. Chem. Kinet., 1989, 21, 157-163. [all data]


Notes

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