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Phenol, 2,6-dichloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - R.L. Brown and S.E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, M. Frenkel director
AC - W.E. Acree, Jr., J.S. Chickos
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
DH - E.S. Domalski and E.D. Hearing

QuantityValueUnitsMethodReferenceComment
Tboil492.2KN/AAldrich Chemical Company Inc., 1990BS
QuantityValueUnitsMethodReferenceComment
Tfus340.0KN/APoeti, Faneli, et al., 1982Uncertainty assigned by TRC = 0.2 K; TRC
QuantityValueUnitsMethodReferenceComment
Deltavap59.6 ± 0.3kJ/molGSVerevkin, Emel'yanenko, et al., 2007Based on data from 341. - 371. K.; AC
Deltavap58.5 ± 0.5kJ/molN/AMokbel, Pauchon, et al., 1995Based on data from 343. - 457. K. See also Verevkin, Emel'yanenko, et al., 2007.; AC
QuantityValueUnitsMethodReferenceComment
Deltasub79.3 ± 0.2kJ/molGSVerevkin, Emel'yanenko, et al., 2007Based on data from 299. - 331. K.; AC
Deltasub75.8 ± 1.0kJ/molCRibeiro Da Silva, Ferrao, et al., 1994HCl (1:600 H2O); ALS
Deltasub75.8 ± 1.1kJ/molCda Silva, 1994AC

Reduced pressure boiling point

Tboil (K)Pressure (bar)ReferenceComment
355.70.005Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol)Temperature (K)MethodReferenceComment
55.4356.GSVerevkin, Emel'yanenko, et al., 2007Based on data from 341. - 371. K.; AC
51.6400.N/AMokbel, Pauchon, et al., 1995Based on data from 343. - 457. K. See also Verevkin, Emel'yanenko, et al., 2007.; AC
57.9348.AStephenson and Malanowski, 1987Based on data from 333. - 493. K. See also Stull, 1947.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K)ABCReferenceComment
332.7 - 493.5.328132431.802-36.391Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol)Temperature (K)ReferenceComment
22.141340.0Poeti, Fanelli, et al., 1982DH
22.14340.Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K)Temperature (K)ReferenceComment
65.12340.0Poeti, Fanelli, et al., 1982DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Poeti, Faneli, et al., 1982
Poeti, G.; Faneli, E.; Braghetti, M.J., A differential scanning calorimetric study of some phenol derivatives, Therm. Anal., 1982, 24, 2, 273. [doi:10.1007/BF01913681] [all data]

Verevkin, Emel'yanenko, et al., 2007
Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Klamt, Andreas, Thermochemistry of Chlorobenzenes and Chlorophenols: Ambient Temperature Vapor Pressures and Enthalpies of Phase Transitions, J. Chem. Eng. Data, 2007, 52, 2, 499-510. [doi:10.1021/je060429r] [all data]

Mokbel, Pauchon, et al., 1995
Mokbel, I.; Pauchon, V.; Jose, J., Vapor pressures and sublimation pressures of 2,4-dichlorophenol, 2,6-dichlorophenol, and 2,4,6-trichlorophenol, ELDATA: Int. Electron. J. Phys. Chem. Data, 1995, 1, 1, 53. [all data]

Ribeiro Da Silva, Ferrao, et al., 1994
Ribeiro Da Silva, M.A.V.; Ferrao, M.L.C.C.H.; Jiye, F., Standard enthalpies of combustion of the six dichlorophenols by rotating-bomb calorimetry, J. Chem. Thermodyn., 1994, 26, 839-846. [all data]

da Silva, 1994
da Silva, M., Standard enthalpies of combustion of the six dichlorophenols by rotating-bomb calorimetry, The Journal of Chemical Thermodynamics, 1994, 26, 8, 839-846. [doi:10.1006/jcht.1994.1100] [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987. [doi:10.1007/978-94-009-3173-2] [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540. [doi:10.1021/ie50448a022] [all data]

Poeti, Fanelli, et al., 1982
Poeti, G.; Fanelli, E.; Braghetti, M., A differential scanning calorimetric study of some phenol derivatives, J. Therm. Anal., 1982, 24(2), 273-279. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1. [doi:10.1063/1.555985] [all data]


Notes

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