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Ethene, chlorotrifluoro-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)9.81 ± 0.03eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
10.6 ± 0.1EISyrvatka, Gil'burd, et al., 1972LLK
9.76SScott and Russell, 1972LLK
9.82PECullen, Frost, et al., 1972LLK
9.84PELake and Thompson, 1970RDSH
10.26PEWittel and Bock, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CCl+16.9 ± 0.1CF3EISyrvatka, Gil'burd, et al., 1972LLK
CClF+14.9 ± 0.1CFEISyrvatka, Gil'burd, et al., 1972LLK
CFCl+15.0 ± 0.1CF2EISyrvatka, Bel'ferman, et al., 1971LLK
CF+16.7 ± 0.1CClF2EISyrvatka, Gil'burd, et al., 1972LLK
C2ClF2+15.9 ± 0.2FEISyrvatka, Gil'burd, et al., 1972LLK
C2F3+15.4 ± 0.1ClEISyrvatka, Gil'burd, et al., 1972LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Syrvatka, Gil'burd, et al., 1972
Syrvatka, B.G.; Gil'burd, M.M.; Bel'ferman, A.L., Mass spectrometric study of chlorofluoro-substituted ethylenes, J. Org. Chem. USSR, 1972, 8, 1587, In original 1553. [all data]

Scott and Russell, 1972
Scott, J.D.; Russell, B.R., Vacuum-ultraviolet spectral studies of several chlorofluoroethylenes, J. Am. Chem. Soc., 1972, 94, 2634. [all data]

Cullen, Frost, et al., 1972
Cullen, W.R.; Frost, D.C.; Leeder, W.R., The ultraviolet and photoelectron spectra of some unsaturated fluorocarbon derivatives, J. Fluorine Chem., 1972, 1, 227. [all data]

Lake and Thompson, 1970
Lake, R.F.; Thompson, H., Photoelectron spectra of halogenated ethylenes, Proc. Roy. Soc. (London), 1970, A315, 323. [all data]

Wittel and Bock, 1974
Wittel, K.; Bock, H., Photoelektronenspekten und molekuleigenschaften. XXVII. Chlor- und bromathylene- beispiele fur anderungen in «pi»- und «sigma»-Systemen, Chem. Ber., 1974, 107, 317. [all data]

Syrvatka, Bel'ferman, et al., 1971
Syrvatka, B.G.; Bel'ferman, A.L.; Gil'burd, M.M.; Moin, F.B., Determination of the dissociation energy of the double bond in some fluorochloro-substituted ethylenes and their ions by electron bombardment, J. Org. Chem. USSR, 1971, 7, 8, In original 9. [all data]


Notes

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