Ethene, chlorotrifluoro-
- Formula: C2ClF3
- Molecular weight: 116.470
- IUPAC Standard InChIKey: UUAGAQFQZIEFAH-UHFFFAOYSA-N
- CAS Registry Number: 79-38-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ethylene, chlorotrifluoro-; Chlorotrifluoroethene; Chlorotrifluoroethylene; CTFE; Genetron 1113; Monochlorotrifluoroethylene; Trifluorochloroethylene; Trifluoromonochloroethylene; Trifluorovinyl Chloride; Trithene; C2F3Cl; 1-Chloro-1,2,2-trifluoroethylene; 2-Chloro-1,1,2-trifluoroethylene; Chlortrifluoraethylen; Daiflon; Ethylene, trifluorochloro-; Fluoroplast 3; Trifluorchlorethylen; 1,1,2-Trifluoro-2-chloroethylene; UN 1082; 1-Chloro-1,2,2-trifluoroethene; Ethene, 1-chloro-1,2,2-trifluoro-
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: 4Na + C2ClF3 = 2C + ClNa + 3FNa
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -376.7 ± 1.3 | kcal/mol | Cm | Kolesov, Zenkov, et al., 1963 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -368.8 ± 1.3 kcal/mol |
By formula: 2H2 + C2ClF3 = C2H3F3 + HCl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -63.98 ± 0.50 | kcal/mol | Chyd | Lacher, Kianpour, et al., 1956 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -64.92 kcal/mol; At 410 K |
By formula: HBr + C2ClF3 = C2HBrClF3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -26.07 ± 0.23 | kcal/mol | Cm | Lacher, Lea, et al., 1950 | gas phase; Heat of hydrobromination at 367°K |
By formula: Cl2 + C2ClF3 = C2Cl3F3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -48.82 ± 0.48 | kcal/mol | Cm | Lacher, McKinley, et al., 1949 | gas phase; Heat of Chlorination at 363 °K |
By formula: Br2 + C2ClF3 = C2Br2ClF3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -31.61 | kcal/mol | Cm | Lacher, Casali, et al., 1956 | gas phase; Heat of bromination |
By formula: C2Br2ClF3 = Br2 + C2ClF3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 31.608 | kcal/mol | Cm | Lacher, Casali, et al., 1956 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kolesov, Zenkov, et al., 1963
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M.,
Standard enthalpy of formation of chlorotrifluoroethylene,
Russ. J. Phys. Chem. (Engl. Transl.), 1963, 37, 115-116. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Lacher, Kianpour, et al., 1956
Lacher, J.R.; Kianpour, A.; Oetting, F.; Park, J.D.,
Reaction calorimetry. The hydrogenation of organic fluorides and chlorides,
Trans. Faraday Soc., 1956, 52, 1500-1508. [all data]
Lacher, Lea, et al., 1950
Lacher, J.R.; Lea, K.R.; Walden, C.H.; Olson, G.G.; Park, J.D.,
Reaction heats of organic fluorine compounds. III. The vapor phase heats of hydrobromination of some simple fluoroolefins,
J. Am. Chem. Soc., 1950, 72, 3231-3234. [all data]
Lacher, McKinley, et al., 1949
Lacher, J.R.; McKinley, J.J.; Walden, C.; Lea, K.; Park, J.D.,
Reaction heats of organic fluorine compounds. II. The vapor phase heats of chlorination of some simple fluoroolefins,
J. Am. Chem. Soc., 1949, 71, 1334-1337. [all data]
Lacher, Casali, et al., 1956
Lacher, J.R.; Casali, L.; Park, J.D.,
Reaction heats of organic halogen compounds V. The vapor phase bromination of tetrafluoroethylene and trifluorochloroethylene,
J. Phys. Chem., 1956, 60, 608-610. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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