Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Ethane, nitro-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H3NO2- + Ethane, nitro- = C4H8N2O4-

By formula: C2H3NO2- + C2H5NO2 = C4H8N2O4-

Quantity Value Units Method Reference Comment
Deltar65.7 ± 3.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar35.6kJ/molTDAsWincel, 2004gas phase; B

C2H4NO2- + Ethane, nitro- = C4H9N2O4-

By formula: C2H4NO2- + C2H5NO2 = C4H9N2O4-

Quantity Value Units Method Reference Comment
Deltar67.8 ± 3.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar37.7kJ/molTDAsWincel, 2004gas phase; B

C2H5N2O4- + 2Ethane, nitro- = C4H10N3O6-

By formula: C2H5N2O4- + 2C2H5NO2 = C4H10N3O6-

Quantity Value Units Method Reference Comment
Deltar62.3 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar28.5kJ/molTDAsWincel, 2004gas phase; B

C2H6NO2+ + Ethane, nitro- = (C2H6NO2+ bullet Ethane, nitro-)

By formula: C2H6NO2+ + C2H5NO2 = (C2H6NO2+ bullet C2H5NO2)

Quantity Value Units Method Reference Comment
Deltar130.kJ/molPHPMSMeot-Ner, Hunter, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar140.J/mol*KPHPMSMeot-Ner, Hunter, et al., 1979gas phase; M

C4H8N2O4- + 2Ethane, nitro- = C6H13N3O6-

By formula: C4H8N2O4- + 2C2H5NO2 = C6H13N3O6-

Quantity Value Units Method Reference Comment
Deltar63.6 ± 3.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar23.8kJ/molTDAsWincel, 2004gas phase; B

C4H9N2O4- + 2Ethane, nitro- = C6H14N3O6-

By formula: C4H9N2O4- + 2C2H5NO2 = C6H14N3O6-

Quantity Value Units Method Reference Comment
Deltar64.4 ± 3.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar25.9kJ/molTDAsWincel, 2004gas phase; B

C4H10N2O6- + 2Ethane, nitro- = C6H15N3O8-

By formula: C4H10N2O6- + 2C2H5NO2 = C6H15N3O8-

Quantity Value Units Method Reference Comment
Deltar53.1 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar18.4kJ/molTDAsWincel, 2004gas phase; B

C4H10N3O6- + 3Ethane, nitro- = C6H15N4O8-

By formula: C4H10N3O6- + 3C2H5NO2 = C6H15N4O8-

Quantity Value Units Method Reference Comment
Deltar49.4 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar16.7kJ/molTDAsWincel, 2004gas phase; B

C6H15N3O6- + 3Ethane, nitro- = C8H20N4O8-

By formula: C6H15N3O6- + 3C2H5NO2 = C8H20N4O8-

Quantity Value Units Method Reference Comment
Deltar56.9 ± 1.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar19.7kJ/molTDAsWincel, 2004gas phase; B

C6H15N3O8- + 3Ethane, nitro- = C8H20N4O10-

By formula: C6H15N3O8- + 3C2H5NO2 = C8H20N4O10-

Quantity Value Units Method Reference Comment
Deltar47.3 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.0kJ/molTDAsWincel, 2004gas phase; B

C6H15N4O8- + 4Ethane, nitro- = C8H20N5O10-

By formula: C6H15N4O8- + 4C2H5NO2 = C8H20N5O10-

Quantity Value Units Method Reference Comment
Deltar46.0 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.3kJ/molTDAsWincel, 2004gas phase; B

C8H20N4O8- + 4Ethane, nitro- = C10H25N5O10-

By formula: C8H20N4O8- + 4C2H5NO2 = C10H25N5O10-

Quantity Value Units Method Reference Comment
Deltar49.8 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.79kJ/molTDAsWincel, 2004gas phase; B

C8H20N4O10- + 4Ethane, nitro- = C10H25N5O12-

By formula: C8H20N4O10- + 4C2H5NO2 = C10H25N5O12-

Quantity Value Units Method Reference Comment
Deltar43.9 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.9kJ/molTDAsWincel, 2004gas phase; B

Nitrogen oxide anion + Ethane, nitro- = C2H5N2O4-

By formula: NO2- + C2H5NO2 = C2H5N2O4-

Quantity Value Units Method Reference Comment
Deltar66.1 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar37.2kJ/molTDAsWincel, 2004gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wincel, 2004
Wincel, H., Gas-phase clustering reactions of NO2-, C2H3NO2-, C2H4NO2-C2H5NO2- and C2H5NO4- with C2H5NO2, Int. J. Mass Spectrom., 2004, 232, 2, 185-194, https://doi.org/10.1016/j.ijms.2004.01.003 . [all data]

Meot-Ner, Hunter, et al., 1979
Meot-Ner, (Mautner); Hunter, E.P.; Field, F.H., Ion Thermochemistry of Low Volatility Compounds in the Gas Phase. I. Intrinsic Basicities of Alpha - Amino Acids, J. Am. Chem. Soc., 1979, 101, 3, 686, https://doi.org/10.1021/ja00497a034 . [all data]


Notes

Go To: Top, Ion clustering data, References