Ethane, nitro-

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H3NO2- + Ethane, nitro- = C4H8N2O4-

By formula: C2H3NO2- + C2H5NO2 = C4H8N2O4-

Quantity Value Units Method Reference Comment
Δr65.7 ± 3.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr35.6kJ/molTDAsWincel, 2004gas phase; B

C2H4NO2- + Ethane, nitro- = C4H9N2O4-

By formula: C2H4NO2- + C2H5NO2 = C4H9N2O4-

Quantity Value Units Method Reference Comment
Δr67.8 ± 3.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr37.7kJ/molTDAsWincel, 2004gas phase; B

C2H5N2O4- + 2Ethane, nitro- = C4H10N3O6-

By formula: C2H5N2O4- + 2C2H5NO2 = C4H10N3O6-

Quantity Value Units Method Reference Comment
Δr62.3 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr28.5kJ/molTDAsWincel, 2004gas phase; B

C2H6NO2+ + Ethane, nitro- = (C2H6NO2+ • Ethane, nitro-)

By formula: C2H6NO2+ + C2H5NO2 = (C2H6NO2+ • C2H5NO2)

Quantity Value Units Method Reference Comment
Δr130.kJ/molPHPMSMeot-Ner, Hunter, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr140.J/mol*KPHPMSMeot-Ner, Hunter, et al., 1979gas phase; M

C4H8N2O4- + 2Ethane, nitro- = C6H13N3O6-

By formula: C4H8N2O4- + 2C2H5NO2 = C6H13N3O6-

Quantity Value Units Method Reference Comment
Δr63.6 ± 3.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr23.8kJ/molTDAsWincel, 2004gas phase; B

C4H9N2O4- + 2Ethane, nitro- = C6H14N3O6-

By formula: C4H9N2O4- + 2C2H5NO2 = C6H14N3O6-

Quantity Value Units Method Reference Comment
Δr64.4 ± 3.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr25.9kJ/molTDAsWincel, 2004gas phase; B

C4H10N2O6- + 2Ethane, nitro- = C6H15N3O8-

By formula: C4H10N2O6- + 2C2H5NO2 = C6H15N3O8-

Quantity Value Units Method Reference Comment
Δr53.1 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr18.4kJ/molTDAsWincel, 2004gas phase; B

C4H10N3O6- + 3Ethane, nitro- = C6H15N4O8-

By formula: C4H10N3O6- + 3C2H5NO2 = C6H15N4O8-

Quantity Value Units Method Reference Comment
Δr49.4 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr16.7kJ/molTDAsWincel, 2004gas phase; B

C6H15N3O6- + 3Ethane, nitro- = C8H20N4O8-

By formula: C6H15N3O6- + 3C2H5NO2 = C8H20N4O8-

Quantity Value Units Method Reference Comment
Δr56.9 ± 1.3kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr19.7kJ/molTDAsWincel, 2004gas phase; B

C6H15N3O8- + 3Ethane, nitro- = C8H20N4O10-

By formula: C6H15N3O8- + 3C2H5NO2 = C8H20N4O10-

Quantity Value Units Method Reference Comment
Δr47.3 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr10.0kJ/molTDAsWincel, 2004gas phase; B

C6H15N4O8- + 4Ethane, nitro- = C8H20N5O10-

By formula: C6H15N4O8- + 4C2H5NO2 = C8H20N5O10-

Quantity Value Units Method Reference Comment
Δr46.0 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr11.3kJ/molTDAsWincel, 2004gas phase; B

C8H20N4O8- + 4Ethane, nitro- = C10H25N5O10-

By formula: C8H20N4O8- + 4C2H5NO2 = C10H25N5O10-

Quantity Value Units Method Reference Comment
Δr49.8 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr8.79kJ/molTDAsWincel, 2004gas phase; B

C8H20N4O10- + 4Ethane, nitro- = C10H25N5O12-

By formula: C8H20N4O10- + 4C2H5NO2 = C10H25N5O12-

Quantity Value Units Method Reference Comment
Δr43.9 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr2.9kJ/molTDAsWincel, 2004gas phase; B

Nitrogen oxide anion + Ethane, nitro- = C2H5N2O4-

By formula: NO2- + C2H5NO2 = C2H5N2O4-

Quantity Value Units Method Reference Comment
Δr66.1 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Δr37.2kJ/molTDAsWincel, 2004gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wincel, 2004
Wincel, H., Gas-phase clustering reactions of NO2-, C2H3NO2-, C2H4NO2-C2H5NO2- and C2H5NO4- with C2H5NO2, Int. J. Mass Spectrom., 2004, 232, 2, 185-194, https://doi.org/10.1016/j.ijms.2004.01.003 . [all data]

Meot-Ner, Hunter, et al., 1979
Meot-Ner, (Mautner); Hunter, E.P.; Field, F.H., Ion Thermochemistry of Low Volatility Compounds in the Gas Phase. I. Intrinsic Basicities of Alpha - Amino Acids, J. Am. Chem. Soc., 1979, 101, 3, 686, https://doi.org/10.1021/ja00497a034 . [all data]


Notes

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