Arsenic trichloride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.2 ± 0.1EIOzgen, 1983LBLHLM
11.6 ± 0.05EIPabst, Sharpe, et al., 1980LLK
10.57 ± 0.03EIJohnstone and Mellon, 1972LLK
10.55 ± 0.025PEJohnstone and Mellon, 1972LLK
10.72 ± 0.07PELloyd, 1970RDSH
11.7 ± 0.1EICullen and Frost, 1962RDSH
10.90PELee and Rabalais, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
As+17.4 ± 0.1?EIOzgen, 1983LBLHLM
As+20.4 ± 0.43ClEIPabst, Sharpe, et al., 1980LLK
AsCl+16.6 ± 0.1Cl2/2ClEIOzgen, 1983LBLHLM
ClAs+17.7 ± 0.2?EIPabst, Sharpe, et al., 1980LLK
AsCl2+12.1 ± 0.1ClEIOzgen, 1983LBLHLM
Cl2As+12.4 ± 0.2Cl-EIPabst, Sharpe, et al., 1980LLK
Cl+22.0 ± 0.1?EIOzgen, 1983LBLHLM


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ozgen, 1983
Ozgen, T., Mass spectrometric determination of the appearance potentials of PCl3, AsCl3, SbCl3, BiCl3 and their fragments, Int. J. Mass Spectrom. Ion Processes, 1983, 48, 427. [all data]

Pabst, Sharpe, et al., 1980
Pabst, R.E.; Sharpe, M.C.; Margrave, J.L.; Franklin, J.L., An electron impact study of the appearance energies of positive ions from AsF3, AsCl3, AsBr3 and AsF5, Int. J. Mass Spectrom. Ion Phys., 1980, 33, 187. [all data]

Johnstone and Mellon, 1972
Johnstone, R.A.W.; Mellon, F.A., Electron-impact ionization and appearance potentials, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1209. [all data]

Lloyd, 1970
Lloyd, D.R., The failure of electron impact measurements to detect first ionization potentials in some molecules, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 500. [all data]

Cullen and Frost, 1962
Cullen, W.R.; Frost, D.C., Ionization potentials of some perfluoroalkyl arsines, Can. J. Chem., 1962, 40, 390. [all data]

Lee and Rabalais, 1974
Lee, T.H.; Rabalais, J.W., Model for spin- orbit interactions with inclusion of d electrons: Applications to photoelectron spectroscopy, J. Chem. Phys., 1974, 60, 1172. [all data]


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