Arsenic trichloride

• Formula: AsCl₃
• Molecular weight: 181.281
• IUPAC Standard InChI: InChI=1S/AsCl3/c2-1(3)4 Copy

  
• IUPAC Standard InChIKey: OEYOHULQRFXULB-UHFFFAOYSA-N Copy
• CAS Registry Number: 7784-34-1
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Arsenic(III) chloride; AsCl3; Arsenous chloride; Arsenous trichloride; Arsenic chloride; Arsenic butter; Arsenious chloride; Butter of arsenic; Chlorure arsenieux; Chlorure d'arsenic; Fuming liquid arsenic; Trichloroarsine; Trichlorure d'arsenic; UN 1560; Arsenic chloride (AsCl3); Arsenic(3+) chloride
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Reaction thermochemistry data
  • Ion clustering data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
  • Switch to calorie-based units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ozgen, 1983
Ozgen, T., Mass spectrometric determination of the appearance potentials of PCl₃, AsCl₃, SbCl₃, BiCl₃ and their fragments, Int. J. Mass Spectrom. Ion Processes, 1983, 48, 427. [all data]

Pabst, Sharpe, et al., 1980
Pabst, R.E.; Sharpe, M.C.; Margrave, J.L.; Franklin, J.L., An electron impact study of the appearance energies of positive ions from AsF₃, AsCl₃, AsBr₃ and AsF₅, Int. J. Mass Spectrom. Ion Phys., 1980, 33, 187. [all data]

Johnstone and Mellon, 1972
Johnstone, R.A.W.; Mellon, F.A., Electron-impact ionization and appearance potentials, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1209. [all data]

Lloyd, 1970
Lloyd, D.R., The failure of electron impact measurements to detect first ionization potentials in some molecules, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 500. [all data]

Cullen and Frost, 1962
Cullen, W.R.; Frost, D.C., Ionization potentials of some perfluoroalkyl arsines, Can. J. Chem., 1962, 40, 390. [all data]

Lee and Rabalais, 1974
Lee, T.H.; Rabalais, J.W., Model for spin- orbit interactions with inclusion of d electrons: Applications to photoelectron spectroscopy, J. Chem. Phys., 1974, 60, 1172. [all data]

Notes

Go To: Top, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.