Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

1-Adamantanol

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus554.2KN/AChickos, Braton, et al., 1991Uncertainty assigned by TRC = 0.002 K; TRC
Quantity Value Units Method Reference Comment
Deltavap60.8kJ/molGCvan Roon, Parsons, et al., 2002AC
Quantity Value Units Method Reference Comment
Deltasub86.8 ± 0.2kJ/molCCharapennikau, Blokhin, et al., 2003AC
Deltasub86.7 ± 0.2kJ/molMECharapennikau, Blokhin, et al., 2003Based on data from 288. - 323. K.; AC
Deltasub87. ± 3.kJ/molVArora and Steele, 1978ALS
Deltasub86.0kJ/molN/AArora and Steele, 1978DRB
Deltasub86.6 ± 2.5kJ/molBGArora and Steele, 1978AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
12.36552.9Charapennikau, Blokhin, et al., 2003, 2AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
6.8369.2Salman and Abas, 1989CAL

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
2.500369.16crystaline, IIIcrystaline, IISalman and Abas, 1989, 2DH
7.130529.16crystaline, IIcrystaline, ISalman and Abas, 1989, 2DH
2.500369.16crystaline, IIIcrystaline, IISalman and Abas, 1988DH
7.130529.16crystaline, IIcrystaline, ISalman and Abas, 1988DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
6.77369.16crystaline, IIIcrystaline, IISalman and Abas, 1989, 2DH
13.25529.16crystaline, IIcrystaline, ISalman and Abas, 1989, 2DH
6.77369.16crystaline, IIIcrystaline, IISalman and Abas, 1988DH
13.25529.16crystaline, IIcrystaline, ISalman and Abas, 1988DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chickos, Braton, et al., 1991
Chickos, J.S.; Braton, C.M.; Hesse, D.G.; Liebman, J.F., Estimating entropies and enthalpies of fusion of organic compounds, J. Org. Chem., 1991, 56, 3, 927, https://doi.org/10.1021/jo00003a007 . [all data]

van Roon, Parsons, et al., 2002
van Roon, André; Parsons, John R.; Govers, Harrie A.J., Gas chromatographic determination of vapour pressure and related thermodynamic properties of monoterpenes and biogenically related compounds, Journal of Chromatography A, 2002, 955, 1, 105-115, https://doi.org/10.1016/S0021-9673(02)00200-5 . [all data]

Charapennikau, Blokhin, et al., 2003
Charapennikau, M.B.; Blokhin, A.V.; Kabo, G.J.; Sevruk, V.M.; Krasulin, A.P., Thermodynamic properties of three adamantanols in the ideal gas state, Thermochimica Acta, 2003, 405, 1, 85-91, https://doi.org/10.1016/S0040-6031(03)00126-6 . [all data]

Arora and Steele, 1978
Arora, M.; Steele, W.V., The standard enthalpies of formation of adamantanoid compounds 5. Adamantanols and adamantanone, J. Chem. Thermodyn., 1978, 10, 403-407. [all data]

Charapennikau, Blokhin, et al., 2003, 2
Charapennikau, M.B.; Blokhin, A.V.; Kabo, A.G.; Kabo, G.J., The heat capacities and parameters of solid phase transitions and fusion for 1- and 2-adamantanols, The Journal of Chemical Thermodynamics, 2003, 35, 1, 145-157, https://doi.org/10.1016/S0021-9614(02)00317-8 . [all data]

Salman and Abas, 1989
Salman, S.R.; Abas, K.F., Thermal behaviour of 2-hydroxyadamantane, Thermochim. Acta, 1989, 142, 2, 245, https://doi.org/10.1016/0040-6031(89)85022-1 . [all data]

Salman and Abas, 1989, 2
Salman, S.R.; Abas, K.F., Thermal behaviour of 2-hydroxyadamantane, Thermmochim. Acta, 1989, 142(2), 245-249. [all data]

Salman and Abas, 1988
Salman, S.R.; Abas, K.F., Thermal behaviour of 2-hydroxyadamantane, Thermochim. Acta, 1988, 136, 81-85. [all data]


Notes

Go To: Top, Phase change data, References