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Ethyl Chloride

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - J.E. Bartmess
M - M. M. Meot-Ner (Mautner) and S. G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Bromine anion + Ethyl Chloride = (Bromine anion bullet Ethyl Chloride)

By formula: Br- + C2H5Cl = (Br- bullet C2H5Cl)

QuantityValueUnitsMethodReferenceComment
Deltar46.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
QuantityValueUnitsMethodReferenceComment
Deltar22.4 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Methyl cation + Ethyl Chloride = (Methyl cation bullet Ethyl Chloride)

By formula: CH3+ + C2H5Cl = (CH3+ bullet C2H5Cl)

QuantityValueUnitsMethodReferenceComment
Deltar300.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; from Et+ + CH3Cl; Cox and Pilcher, 1970, Rosenstock, Buff, et al., 1982; Sen Sharma and Kebarle, 1978; M

(C2H5+ bullet Ethyl Chloride) + Ethyl Chloride = (C2H5+ bullet 2Ethyl Chloride)

By formula: (C2H5+ bullet C2H5Cl) + C2H5Cl = (C2H5+ bullet 2C2H5Cl)

QuantityValueUnitsMethodReferenceComment
Deltar22.kJ/molHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable; M
QuantityValueUnitsMethodReferenceComment
Deltar36.J/mol*KHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable; M

(C2H5+ bullet 2Ethyl Chloride) + Ethyl Chloride = (C2H5+ bullet 3Ethyl Chloride)

By formula: (C2H5+ bullet 2C2H5Cl) + C2H5Cl = (C2H5+ bullet 3C2H5Cl)

QuantityValueUnitsMethodReferenceComment
Deltar20.kJ/molHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable; M
QuantityValueUnitsMethodReferenceComment
Deltar32.J/mol*KHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable; M

C4H9+ + Ethyl Chloride = (C4H9+ bullet Ethyl Chloride)

By formula: C4H9+ + C2H5Cl = (C4H9+ bullet C2H5Cl)

QuantityValueUnitsMethodReferenceComment
Deltar38.kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar68.2J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; M

Chlorine anion + Ethyl Chloride = (Chlorine anion bullet Ethyl Chloride)

By formula: Cl- + C2H5Cl = (Cl- bullet C2H5Cl)

QuantityValueUnitsMethodReferenceComment
Deltar51.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar61. ± 19.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984; B
QuantityValueUnitsMethodReferenceComment
Deltar28.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B., High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions., J. Am. Chem. Soc., 1996, 118, 39, 9360. [doi:10.1021/ja960565o] [all data]

Sharma, Meza de Hojer, et al., 1985
Sharma, D.M.S.; Meza de Hojer, S.; Kebarle, P., Stabilities of halonium ions from a study of gas-phase equilibria R+ + XR' = (RXR')+, J. Am. Chem. Soc., 1985, 107, 13, 3757. [doi:10.1021/ja00299a002] [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Rosenstock, Buff, et al., 1982
Rosenstock, H.M.; Buff, R.; Ferreira, M.A.A.; Lias, S.G.; Parr, A.C.; Stockbauer, R.L.; Holmes, J.L., Fragmentation mechanism and energetics of some alkyl halide ions, J. Am. Chem. Soc., 1982, 104, 2337. [all data]

Sen Sharma and Kebarle, 1978
Sen Sharma, D.K.; Kebarle, P., Binding Energies and Stabilities of Chloronium Ions from Study of the Gas - Phase Equilibria: R1+ + ClR2 = R1ClR2+, J. Am. Chem. Soc., 1978, 100, 18, 5826. [doi:10.1021/ja00486a039] [all data]

Luczynski and Wincel, 1974
Luczynski, Z.; Wincel, H., Ion - Molecule Reactions in Ethyl Chloride, Int. J. Mass Spectrom. Ion Phys., 1974, 14, 1, 29. [doi:10.1016/0020-7381(74)80059-8] [all data]

Riveros, Breda, et al., 1973
Riveros, J.M.; Breda, A.C.; Blair, L.K., Formation and relative stability of chloride ion clusters in the gas phase by ICR spectroscopy, J. Am. Chem. Soc., 1973, 95, 4066. [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ion cyclotron resonance halide-exchange equilibria, J. Phys. Chem., 1984, 88, 1083. [all data]


Notes

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