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Liquid Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1685. - 3504.616
A 27.19604
B -1.198306×10-10
C 5.353262×10-11
D -6.956612×10-12
E -4.294375×10-12
F 40.36163
G 77.37178
H 48.46997
ReferenceChase, 1998
Comment Data last reviewed in March, 1967
Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
1685.27.2091.5669.1837.72
1700.27.2091.8069.3838.12
1800.27.2093.3670.6740.84
1900.27.2094.8371.9043.56
2000.27.2096.2273.0846.28
2100.27.2097.5574.2149.00
2200.27.2098.8175.3051.72
2300.27.20100.076.3554.44
2400.27.20101.277.3657.16
2500.27.20102.378.3459.88
2600.27.20103.479.2862.60
2700.27.20104.480.1965.32
2800.27.20105.481.0768.04
2900.27.20106.381.9370.76
3000.27.20107.282.7673.48
3100.27.20108.183.5676.20
3200.27.20109.084.3478.92
3300.27.20109.885.1081.64
3400.27.20110.785.8484.36
3500.27.20111.486.5687.08

References

Go To: Top, Liquid Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Liquid Phase Heat Capacity (Shomate Equation), References