1-Propene, 1-(1,1-dimethoxyethoxy)-, (Z)-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

1,1-Dimethoxyethyl allyl ether = 1-Propene, 1-(1,1-dimethoxyethoxy)-, (Z)-

By formula: C7H14O3 = C7H14O3

Quantity Value Units Method Reference Comment
Δr-20.1 ± 0.3kJ/molEqkTaskinen, 1993liquid phase; solvent: DMSO; Isomerization

Dimethyl(E)-1-propenyl orthoacetate = 1-Propene, 1-(1,1-dimethoxyethoxy)-, (Z)-

By formula: C7H14O3 = C7H14O3

Quantity Value Units Method Reference Comment
Δr-3.0 ± 0.6kJ/molEqkTaskinen and Lahteenmaki, 1978liquid phase; solvent: Neat

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taskinen, 1993
Taskinen, E., Relative thermodynamic stabilities of isomeric alkyl allyl and alkyl (Z)-propenyl ethers, Tetrahedron, 1993, 49, 11389-11394. [all data]

Taskinen and Lahteenmaki, 1978
Taskinen, E.; Lahteenmaki, H., Thermodynamics of vinyl ethers. Part XX. α,β-Unsaturated orthoesters, Finn. Chem. Lett., 1978, 47-50. [all data]


Notes

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