Benzyl sulfone

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tfus422.7KN/AKaldor and Hammond, 1991Uncertainty assigned by TRC = 1. K; TRC
Tfus425.KN/AJarvis, Hoey, et al., 1988Uncertainty assigned by TRC = 3. K; TRC
Tfus402.KN/AOlah and Gupta, 1983Uncertainty assigned by TRC = 2. K; TRC
Tfus425.KN/ABoehme and Sitorus, 1972Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Δsub27.3 ± 0.5kcal/molVMackle and O'Hare, 1961Haet of combustion corrected for pressure; ALS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kaldor and Hammond, 1991
Kaldor, S.W.; Hammond, M., A Mild Osmium Tetraoxide-Catalyzed Method for the Oxidation of Sulfides to Sulfones, Tetrahedron Lett., 1991, 32, 5043-6. [all data]

Jarvis, Hoey, et al., 1988
Jarvis, W.T.; Hoey, M.D.; Finocchio, A.L.; Dittmar, D.C., Organic reactions of Reduced Species of Sulfur Dioxide, J. Org. Chem., 1988, 53, 5750-6. [all data]

Olah and Gupta, 1983
Olah, G.A.; Gupta, B.G.B., Onium Ions 27. Oxidation of Sulfoxides to Sulfones with Nitronium Salts, J. Org. Chem., 1983, 48, 3585-7. [all data]

Boehme and Sitorus, 1972
Boehme, V.H.; Sitorus, U., Oxidation of Thioethers to Sulfones with Hydrogen Peroxide in Alkaline Solution, Chem.-Ztg., 1972, 96, 37-8. [all data]

Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 6 - Heats of combustion, fusion, vaporization and atomization of six aromatic and two allylic sulphones, Trans. Faraday Soc., 1961, 57, 1521-1526. [all data]


Notes

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