2-(2-Methylvinyloxy)-4-methyl-1-pentene


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2-(2-Methylvinyloxy)-4-methyl-1-pentene = 2-Pentene, 4-methyl-2-[(1-methylethenyl)oxy]-, (Z)-

By formula: C9H16O = C9H16O

Quantity Value Units Method Reference Comment
Δr-10.1 ± 0.5kJ/molEqkTaskinen and Virtanen, 1977liquid phase; solvent: Cyclohexane
Δr-10.9 ± 0.6kJ/molEqkTaskinen and Virtanen, 1977gas phase; solvent: Cyclohexane; Gas phase isomerization

2-(2-Methylvinyloxy)-4-methyl-1-pentene = (E) 2-(2-Methylvinyoxy)-4-methyl-2-pentene

By formula: C9H16O = C9H16O

Quantity Value Units Method Reference Comment
Δr-4.7 ± 0.3kJ/molEqkTaskinen and Virtanen, 1977liquid phase; solvent: Cyclohexane
Δr-4.3 ± 0.4kJ/molEqkTaskinen and Virtanen, 1977gas phase; solvent: Cyclohexane; Gas phase isomerization

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taskinen and Virtanen, 1977
Taskinen, E.; Virtanen, R., Thermocynamics of vinyl ethers. 19. Alkyl-substituted divinyl ethers, J. Org. Chem., 1977, 42, 1443-1449. [all data]


Notes

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