Cyclohexanone, 2-methyl-5-(1-methylethenyl)-, trans-
- Formula: C10H16O
- Molecular weight: 152.2334
- IUPAC Standard InChIKey: AZOCECCLWFDTAP-RKDXNWHRSA-N
- CAS Registry Number: 5948-04-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: p-Menth-8-en-2-one, trans-; trans-Dihydrocarvone; Carvone, Dihydro-, trans; p-Menth-8-en-2-one, E-; 5-Isopropenyl-2-methylcyclohexanone, trans; Dihydrocarvone; Cyclohexanone, 2-methyl-5-(1-methylethenyl)-, (2R,5R)-rel-; (2R,5R)-2-methyl-5-prop-1-en-2-ylcyclohexan-1-one
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- Information on this page:
- Other data available:
- Options:
Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | DB-5 MS | HP-5 MS | OV-101 | DB-5 MS |
Column length (m) | 30. | 60. | 30. | 50. | 60. |
Carrier gas | Helium | Helium | Helium | Helium | Helium |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 40. | 70. | 70. | 40. |
Tend (C) | 240. | 250. | 290. | 220. | 330. |
Heat rate (K/min) | 3. | 5. | 5. | 2. | 2. |
Initial hold (min) | 15. | 12. | |||
Final hold (min) | 15. | 10. | 30. | ||
I | 1190. | 1201. | 1208. | 1182. | 1205. |
Reference | Alizadeh, Khosh-Khui, et al., 2011 | Mesa-Arango, Betancur-Galvis, et al., 2010 | Radulovic, Dordevic, et al., 2010 | Benites, Moiteiro, et al., 2009 | Patil, Jayaprakasha, et al., 2009 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 MS | CP Sil 5 CB | RTX-5 MS | HP-5 | HP-5 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | Helium | N2 | He | N2 | N2 |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 40. | 50. | 45. | 50. | 50. |
Tend (C) | 250. | 200. | 210. | 280. | 280. |
Heat rate (K/min) | 4. | 5. | 3. | 9. | 9. |
Initial hold (min) | 2. | 3. | 3. | ||
Final hold (min) | 2. | 3. | 3. | ||
I | 1203. | 1182. | 1203. | 1202. | 1208. |
Reference | Su, Wang, et al., 2009 | Hnawia, Cabalion, et al., 2007 | Hudaib and Aburjai, 2007 | Abdelwahed, Hayder, et al., 2006 | Abdelwahed, Hayder, et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | BP-1 | DB-5 | HP-5 | HP-5 | HP-5MS |
Column length (m) | 50. | 30. | 30. | 60. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.22 | 0.25 | 0.25 | 0.32 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 50. | 50. | 30. | 60. |
Tend (C) | 220. | 250. | 300. | 260. | 275. |
Heat rate (K/min) | 2. | 3. | 5. | 2. | 15. |
Initial hold (min) | 5. | 2. | |||
Final hold (min) | 20. | 10. | 5. | 28. | |
I | 1171. | 1200. | 1218. | 1200.4 | 1200. |
Reference | Boti, Muselli, et al., 2006 | Havlik, Kokoska, et al., 2006 | Figuérédo, Cabassu, et al., 2005 | Leffingwell and Alford, 2005 | Shams-Ardakani, Ghannadi, et al., 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | DB-5 | DB-5 | HP-5 | HP-5 |
Column length (m) | 30. | 30. | 60. | 30. | 60. |
Carrier gas | He | He | He | Helium | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.32 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | ||
Tstart (C) | 60. | 60. | 50. | 70. | 40. |
Tend (C) | 230. | 240. | 220. | 210. | 250. |
Heat rate (K/min) | 3. | 4. | 3. | 2. | 5. |
Initial hold (min) | 15. | ||||
Final hold (min) | 20. | 60. | |||
I | 1201. | 1195. | 1213. | 1204. | 1197. |
Reference | Skoula and Grayer, 2005 | Cabanillas, Lopez, et al., 2003 | Edris, Shalaby, et al., 2003 | Mookdasanit, Tamura, et al., 2003 | Stashenko, Jaramillo, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | HP-5 | HP-5 | BP-1 | HP-5 |
Column length (m) | 30. | 30. | 30. | 25. | 30. |
Carrier gas | He | N2 | N2 | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.33 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 1.0 | 0.25 |
Tstart (C) | 60. | 60. | 60. | 60. | 60. |
Tend (C) | 240. | 240. | 220. | 275. | 275. |
Heat rate (K/min) | 3. | 3. | 5. | 4. | 4. |
Initial hold (min) | 10. | ||||
Final hold (min) | |||||
I | 1202. | 1210. | 1202. | 1199. | 1202. |
Reference | Kobaisy, Tellez, et al., 2002 | Novak, Langbehn, et al., 2002 | Gallori, Flamini, et al., 2001 | Mohagheghzadeh, Shams-Ardakani, et al., 2000 | Mohagheghzadeh, Shams-Ardakani, et al., 2000, 2 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary |
---|---|---|
Active phase | HP-5 | HP-5 |
Column length (m) | ||
Carrier gas | ||
Substrate | ||
Column diameter (mm) | ||
Phase thickness (μm) | ||
Tstart (C) | 40. | 40. |
Tend (C) | 210. | 210. |
Heat rate (K/min) | 2. | 2. |
Initial hold (min) | ||
Final hold (min) | ||
I | 1197. | 1197. |
Reference | Collin, Deslauriers, et al., 1993 | Collin, Deslauriers, et al., 1993 |
Comment | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Alizadeh, Khosh-Khui, et al., 2011
Alizadeh, A.; Khosh-Khui, M.; Javidnia, K.; Firuzi, O.; Jokar, S.M.,
Chemical composition of the essential oil, total phenolic content and antioxidant activity in Origanum maiorana L. (Lamiaceae) cultivated in Iran,
Adv. Environ. Biol., 2011, 5, 8, 2326-2331. [all data]
Mesa-Arango, Betancur-Galvis, et al., 2010
Mesa-Arango, A.C.; Betancur-Galvis, L.; Montiel, J.; Bueno, J.G.; Baena, A.; Duran, D.C.; Martinez, J.R.; Stashenko, E.E.,
Antifungal activity and chemical composition of the essential oils of Lippia alba (Miller) N.E. Brown grown in different regions of Colombia,
J. Essential Oil Res., 2010, 22, 6, 568-574, https://doi.org/10.1080/10412905.2010.9700402
. [all data]
Radulovic, Dordevic, et al., 2010
Radulovic, N.; Dordevic, N.; Markovic, M.; Palic, R.,
Volatile constituents of Glechoma Hirsuta Waldst. Kit. and G. Hederacea L. (Lamiaceae),
Bull. Chem. Soc. Ethiop., 2010, 24, 1, 67-76, https://doi.org/10.4314/bcse.v24i1.52962
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Benites, Moiteiro, et al., 2009
Benites, J.; Moiteiro, C.; Miguel, G.; Rojo, L.; Lopez, J.; Venancio, F.; Ramalho, L.; Feio, S.; Dandlen, S.; Casanova, H.; Torres, I.,
Composition and biological activity of the essential oil of Peruvial Lantana camara,
J. Chilean Chem. Soc., 2009, 54, 4, 379-384, https://doi.org/10.4067/S0717-97072009000400012
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Patil, Jayaprakasha, et al., 2009
Patil, J.R.; Jayaprakasha, G.K.; Murthy, K.N.C.; Tichy, S.E.; Chetti, M.B.; Patil, B.S.,
Apoptosis-mediated proliferation inhibition of human colon cancer cells by volatile principles of Citrus auratifolia,
Food Chem., 2009, 114, 4, 1351-1358, https://doi.org/10.1016/j.foodchem.2008.11.033
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Su, Wang, et al., 2009
Su, Y.; Wang, C.; Yinlong, G.,
Analysis of volatile compounds from Mentha hapioealyx Briq. by GC-MS based on accurate mass measurements and retention indices,
Acta Chem. Sinica, 2009, 67, 6, 546-554. [all data]
Hnawia, Cabalion, et al., 2007
Hnawia, E.; Cabalion, P.; Raunicher, I.; Waikedre, J.; Patissou, J.; Buchbauer, G.; Menut, C.,
The leaf essential oil of Murraya crenulata (Turcz.) Oliver from New Caledonia,
Flavour Fragr. J., 2007, 22, 1, 32-34, https://doi.org/10.1002/ffj.1745
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Hudaib and Aburjai, 2007
Hudaib, M.; Aburjai, T.,
Volatile components of Thymus vulgaris L. from wild-growing and cultivated plants in Jordan,
Flavour Fragr. J., 2007, 22, 4, 322-327, https://doi.org/10.1002/ffj.1800
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Abdelwahed, Hayder, et al., 2006
Abdelwahed, A.; Hayder, N.; Kilani, S.; Mahmoud, A.; Chibani, J.; Hammami, M.; Chekir-Ghedira, L.; Ghedira, K.,
Chemical composition and antimicrobial activity of essential oils from Tunisian Pituranthos tortuosus (Coss.) Maire,
Flavour Fragr. J., 2006, 21, 1, 129-133, https://doi.org/10.1002/ffj.1542
. [all data]
Boti, Muselli, et al., 2006
Boti, J.B.; Muselli, A.; Tomi, F.; Koukoua, G.; N'Guessan, T.Y.; Costa, J.; Casanova, J.,
Combined analysis of Cymbopogon giganteus Chiov. leaf oil from Ivory Coast by GC/RI, GC/MS and 13C-NMR,
C.R. Chim., 2006, 9, 1, 164-168, https://doi.org/10.1016/j.crci.2005.10.003
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Havlik, Kokoska, et al., 2006
Havlik, J.; Kokoska, L.; Vasickova, S.; Valterova, I.,
Chemical composition of essential oil from the seeds of Nigella arvensis L. and assessment of its actimicrobial activity,
Flavour Fragr. J., 2006, 21, 4, 713-717, https://doi.org/10.1002/ffj.1713
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Figuérédo, Cabassu, et al., 2005
Figuérédo, G.; Cabassu, P.; Chalchat, J.-C.; Pasquier, B.,
Studies of Mediterranean oregano populations- V. Chemical composition of essential oils of oregano: Origanum syriacum L. var. bevanii (Holmes) Ietswaart, O. syriacum L. var. sinaicum (Boiss.) Ietswaart, and O. syriacum L. var. syriacum from Lebanon and Israel,
Flavour Fragr. J., 2005, 20, 164-168. [all data]
Leffingwell and Alford, 2005
Leffingwell, J.C.; Alford, E.D.,
Volatile constituents of Perique tobacco,
Electron. J. Environ. Agric. Food Chem., 2005, 4, 2, 899-915. [all data]
Shams-Ardakani, Ghannadi, et al., 2005
Shams-Ardakani, M.; Ghannadi, A.; Badr, P.; Mohagheghzadeh, A.,
Biotransformation of terpenes and related compounds by suspension culture of Glycyrrhiza glabra L. (Papilionaceae),
Flavour Fragr. J., 2005, 20, 2, 141-144, https://doi.org/10.1002/ffj.1401
. [all data]
Skoula and Grayer, 2005
Skoula, M.; Grayer, R.J.,
Volatile oils of Coridothymus capitatus, Satureja thymbra, Satureja spinosa and Thymbra calostachya (Lamiaceae) from Crete,
Flavour Fragr. J., 2005, 20, 6, 573-576, https://doi.org/10.1002/ffj.1489
. [all data]
Cabanillas, Lopez, et al., 2003
Cabanillas, C.M.; Lopez, M.L.; Daniele, G.; Zygadlo, J.A.,
Essential oil composition of Aloysia polystachya (Griseb.) Moldenke under rust disease,
Flavour Fragr. J., 2003, 18, 5, 446-448, https://doi.org/10.1002/ffj.1249
. [all data]
Edris, Shalaby, et al., 2003
Edris, A.E.; Shalaby, A.S.; Fadel, H.M.; Abdel-Wahab, M.A.,
Evaluation of a chemotype of spearmint (Mentha spicata L.) grown in Siwa Oasis, Egypt,
Eur. Food Res. Technol., 2003, 218, 1, 74-78, https://doi.org/10.1007/s00217-003-0802-4
. [all data]
Mookdasanit, Tamura, et al., 2003
Mookdasanit, J.; Tamura, H.; Yoshizawa T.; Tokunaga T.; Nakanishi, K.,
Trace Volatile Compounds in Essential Oil of Citrus Sudachi by Means of Modified Solvent Extraction Method,
Food Sci Technol. Res., 2003, 9, 1, 54-61, https://doi.org/10.3136/fstr.9.54
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Stashenko, Jaramillo, et al., 2003
Stashenko, E.E.; Jaramillo, B.E.; Martínez, J.R.,
Comparación de la composición química y de la actividad antioxidante in vitro de los metabolitos secundarios volátiles de plantas de la familia verbenaceae,
Rev. Acad. Colomb. Cienc. Exactas Fis. Nat., 2003, 27, 105, 579-597. [all data]
Kobaisy, Tellez, et al., 2002
Kobaisy, M.; Tellez, M.R.; Dayan, F.E.; Duke, S.O.,
Phytotoxicity and volatile constituents from leaves of Callicarpa japonica Thunb.,
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Novak, Langbehn, et al., 2002
Novak, J.; Langbehn, J.; Pank, F.; Franz. C.M.,
Essential oil compounds in a historical sample of marjoram (Origanum majorana L., Lamiaceae),
Flavour Fragr. J., 2002, 17, 3, 175-180, https://doi.org/10.1002/ffj.1077
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Gallori, Flamini, et al., 2001
Gallori, S.; Flamini, G.; Bilia, A.R.; Morelli, I.; Landini, A.; Vincieri, F.F.,
Chemical composition of some traditional herbal drug preparations: essential oil and aromatic water of costmary (Balsamita suaveolens Pers.),
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Mohagheghzadeh, Shams-Ardakani, et al., 2000
Mohagheghzadeh, A.; Shams-Ardakani, M.; Ghannadi, A.,
Linalol-rich essential oil of Zataria multiflora Boiss. (Lamiaceae),
Flavour Fragr. J., 2000, 15, 2, 119-122, https://doi.org/10.1002/(SICI)1099-1026(200003/04)15:2<119::AID-FFJ878>3.0.CO;2-V
. [all data]
Mohagheghzadeh, Shams-Ardakani, et al., 2000, 2
Mohagheghzadeh, A.; Shams-Ardakani, M.; Ghannadi, A.,
Volatile constituents of callus and flower-bearing tops of Zataria multiflora Boiss. (Lamiaceae),
Flavour Fragr. J., 2000, 15, 6, 373-376, https://doi.org/10.1002/1099-1026(200011/12)15:6<373::AID-FFJ923>3.0.CO;2-9
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Collin, Deslauriers, et al., 1993
Collin, G.J.; Deslauriers, H.; Pageau, N.; Gagnon, M.,
Essential oil of Tansy (Tanacetum vulgare L.) of Canadian origin,
J. Essent. Oil Res., 1993, 5, 6, 629-638, https://doi.org/10.1080/10412905.1993.9698296
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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