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Phenol, m-tert-butyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltavap17.0 ± 0.2kcal/molGSVerevkin, 1999Based on data from 320. - 348. K.; AC
Quantity Value Units Method Reference Comment
Deltasub21.2 ± 0.1kcal/molCRibeiro da Silva, Matos, et al., 1999AC
Deltasub20.6 ± 0.1kcal/molGSVerevkin, 1999Based on data from 278. - 319. K.; AC
Deltasub22.00kcal/molCBertholon, Giray, et al., 1971ALS
Deltasub22.9kcal/molN/ABertholon, Giray, et al., 1971DRB

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
16.5 ± 0.2334.GSVerevkin, 1999Based on data from 320. - 348. K.; AC
14.9406.AStephenson and Malanowski, 1987Based on data from 391. - 524. K.; AC
13.5398.N/AStage, Müller, et al., 1953Based on data from 391. - 524. K.; AC
13.0423.N/AStage, Müller, et al., 1953Based on data from 391. - 524. K.; AC
11.9473.N/AStage, Müller, et al., 1953Based on data from 391. - 524. K.; AC

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
16.9281.AStephenson and Malanowski, 1987Based on data from 266. - 299. K.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Verevkin, 1999
Verevkin, S.P., Thermochemistry of phenols: quantification of theortho-,para-, andmeta-interactions in tert-alkyl substituted phenols, The Journal of Chemical Thermodynamics, 1999, 31, 5, 559-585, https://doi.org/10.1006/jcht.1998.0459 . [all data]

Ribeiro da Silva, Matos, et al., 1999
Ribeiro da Silva, M.A.V.; Matos, M.A.R.; Morais, V.M.F.; Miranda, M.S., Thermochemical and Theoretical Study of tert -Butyl and Di- tert -butylphenol Isomers, J. Org. Chem., 1999, 64, 24, 8816-8820, https://doi.org/10.1021/jo990801o . [all data]

Bertholon, Giray, et al., 1971
Bertholon, G.; Giray, M.; Perrin, R.; Vincent-Falquet-Berny, M.F., No. 532. - Etude physicochimique des phenols. OX. - Ethanlpies de combustion et energies de resonance des alcoyl et aryphenols, Bull. Soc. Chim. France, 1971, 3180-3187. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stage, Müller, et al., 1953
Stage, H.; Müller, E.; Faldix, P., Erdol u Kohle, 1953, 6, 375. [all data]


Notes

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