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L-Asparagine, hydrate (1:1)

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-1086.6 ± 0.84kJ/molCcbHuffman, Ellis, et al., 1936Reanalyzed by Cox and Pilcher, 1970, Original value = -1090.2 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-1916.6 ± 0.79kJ/molCcbHuffman, Ellis, et al., 1936Reanalyzed by Cox and Pilcher, 1970, Original value = -1916.1 ± 0.79 kJ/mol; ALS
Deltacsolid-1924.7kJ/molCcbEmery and Benedict, 1911ALS
Quantity Value Units Method Reference Comment
solid,1 bar209.62J/mol*KN/AHutchens, Cole, et al., 1963DH
solid,1 bar213.4J/mol*KN/AHuffman and Borsook, 1932Extrapolation below 90 K, 56.78 J/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
207.90298.15Hutchens, Cole, et al., 1963T = 10 to 310 K.; DH
205.9296.7Huffman and Borsook, 1932T = 90 to 297 K. Value is unsmoothed experimental datum.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Huffman, Ellis, et al., 1936
Huffman, H.M.; Ellis, E.L.; Fox, S.W., Thermal data. VI. The heats of combustion and free energies of seven organic compounds containing nitrogen, J. Am. Chem. Soc., 1936, 58, 1728-1733. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Emery and Benedict, 1911
Emery, A.G.; Benedict, F.G., The heat of combustion of compounds of physiological importance, Am. J. Physiol., 1911, 28, 301-307. [all data]

Hutchens, Cole, et al., 1963
Hutchens, J.O.; Cole, A.G.; Robie, R.A.; Stout, J.W., Heat capacities from 11 to 305 K, entropies, and free energies of formation of L-aspartic acid, L-glutamic acid, and L-glutamine, J. Biol. Chem., 1963, 238, 2407-2412. [all data]

Huffman and Borsook, 1932
Huffman, H.M.; Borsook, H., Thermal data. I. The heat capacities, entropies and free energies of seven organic compounds containing nitrogen, J. Am. Chem. Soc., 1932, 54, 4297-4301. [all data]


Notes

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