Carbon tetrabromide
- Formula: CBr4
- Molecular weight: 331.627
- IUPAC Standard InChIKey: HJUGFYREWKUQJT-UHFFFAOYSA-N
- CAS Registry Number: 558-13-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methane, tetrabromo-; Carbon bromide (CBr4); Methane tetrabromide; Tetrabromomethane; CBr4; Carbon bromide; Bromid uhlicity; UN 2516; NSC 6179
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 7.03 ± 0.81 | kcal/mol | Ccb | Bickerton, Minas Da Piedade, et al., 1984 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -101.1 ± 0.79 | kcal/mol | Ccb | Bickerton, Minas Da Piedade, et al., 1984 | ALS |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
38.79 | 373. | Kurbatov, 1948 | T = 96 to 182°C. Mean Cp, three temperatures.; DH |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
34.87 | 298.15 | Bickerton, Minas Da Piedade, et al., 1984 | Cp given as 0.44 J/g*K.; DH |
30.750 | 300.6 | Marshall, Staveley, et al., 1956 | T = 22 to 84°C.; DH |
35.47 | 298. | Frederick and Hildebrand, 1939 | T = 298 to 423 K.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bickerton, Minas Da Piedade, et al., 1984
Bickerton, J.; Minas Da Piedade, M.E.; Pilcher, G.,
Enthalpy of formation of tetrabromomethane by rotating-bomb calorimetry,
J. Chem. Thermodyn., 1984, 16, 661-668. [all data]
Kurbatov, 1948
Kurbatov, V.Ya.,
Heat capacity of liquids. 2. Heat capacity and the temperature dependence of heat capacity from halogen derivatives of acylic hydrocarbons,
Zh. Obshch. Kim., 1948, 18, 372-389. [all data]
Marshall, Staveley, et al., 1956
Marshall, J.G.; Staveley, L.A.K.; Hart, K.R.,
A thermodynamic investigation of the transitions in carbon tetrabromide and ammonium chloride,
Trans. Faraday Soc., 1956, 52, 19-31. [all data]
Frederick and Hildebrand, 1939
Frederick, K.J.; Hildebrand, J.H.,
Specific heats and heats of fusion and transition of carbon tetrabromide,
J. Am. Chem. Soc., 1939, 61, 1555-1558. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Cp,solid Constant pressure heat capacity of solid ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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