dimethylcadmium

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   D3h'(G+36)     Symmetry Number σ = 6


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1' 1 CH3 s-str 2903  C  ia 2903 S p liq. Free rotation
a1' 2 CH3 s-deform 1127  C  ia 1127 S p liq. Free rotation
a1' 3 CCd s-str 459  C  ia 459 S p liq. Free rotation
a1 4 Torsion  ia  ia Free rotation
a2 5 CH3 s-str 2923  C 2923 S gas  ia Free rotation
a2 6 CH3 s-deform 1136  C 1136 M gas  ia Free rotation
a2 7 CCd a-str 535  C 535 S gas  ia Free rotation
e' 8 CH3 d-str 2980  C 2980 VS gas Free rotation
e' 9 CH3 d-deform 1315  C 1315 gas 1324 liq. Free rotation
e' 10 CH3 rock 700  C 700 S gas Free rotation
e' 11 CCdC deform 124  C 124 W gas 120 W b liq. Free rotation
e 12 CH3 d-str 2859  C 2859 gas 2834 M liq. Free rotation
e 13 CH3 d-deform 1427  C 1427 W liq. Free rotation
e 14 CH3 rock 634  C 634 M dp liq. Free rotation

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
WWeak
iaInactive
bBroad
pPolarized
dpDepolarized
C3~6 cm-1 uncertainty

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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