cis-1-Propenyl ethyl ether


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Allyl ethyl ether = cis-1-Propenyl ethyl ether

By formula: C5H10O = C5H10O

Quantity Value Units Method Reference Comment
Δr-5.1 ± 0.1kcal/molEqkTaskinen, 1993liquid phase; solvent: DMSO; Isomerization

cis-1-Propenyl ethyl ether = trans-CH3CH=CH-OC2H5

By formula: C5H10O = C5H10O

Quantity Value Units Method Reference Comment
Δr0.372 ± 0.028kcal/molEqkOkuyama, Fueno, et al., 1969liquid phase; GC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taskinen, 1993
Taskinen, E., Relative thermodynamic stabilities of isomeric alkyl allyl and alkyl (Z)-propenyl ethers, Tetrahedron, 1993, 49, 11389-11394. [all data]

Okuyama, Fueno, et al., 1969
Okuyama, T.; Fueno, T.; Furukawa, J., Structure and reactivity of α,β-unsaturated ethers. 9. Cis-trans isomerization equilibriums in the liquid phase, Tetrahedron, 1969, 25, 5409-5414. [all data]


Notes

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