Cyclobutaphosphane, tetrakis(trifluoromethyl)-
- Formula: C4F12P4
- Molecular weight: 399.9187
- IUPAC Standard InChIKey: TVWVWIPMQJSXJS-UHFFFAOYSA-N
- CAS Registry Number: 393-02-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Tetraphosphetane,tetrakis(trifluoromethyl)-; 1,2,3,4Tetra-kis(trifluoromethyl)cyclotetraphosphine
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.5 | PE | Elbel, Egsgaard, et al., 1988 | LL |
10.12 | PE | Elbel, Egsgaard, et al., 1988 | Vertical value; LL |
10.18 | PE | Cowley, Dewar, et al., 1978 | Vertical value; LLK |
10.18 | PE | Cowley, Dewar, et al., 1974 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Elbel, Egsgaard, et al., 1988
Elbel, S.; Egsgaard, H.; Carlsen, L.,
Ionization energies and thermal fragmentation patterns of gaseous cyclopolyarsanes and phosphanes En, Rn(E = As or P;R = Me, Bu, or CF3; n = 3-5): A joint temperature-variable field ionization mass spectrometric and ultraviolet photoelectron spectroscopic study,
J. Chem. Soc. Dalton Trans., 1988, 195. [all data]
Cowley, Dewar, et al., 1978
Cowley, A.H.; Dewar, M.J.S.; Lattman, M.; Mills, J.L.; McKee, M.,
An ultraviolet photoelectron spectroscopic molecular orbital study of some cyclopolyphosphines,
J. Am. Chem. Soc., 1978, 100, 3349. [all data]
Cowley, Dewar, et al., 1974
Cowley, A.H.; Dewar, M.J.S.; Goodman, D.W.; Padolina, M.C.,
A photoelectron spectroscopic study of polyphosphines. The question of pπ:dπ bonding,
J. Am. Chem. Soc., 1974, 96, 3666. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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