Dehydroepiandrosterone, (3β)-, TMS derivative

• Formula: C₂₂H₃₆O₂Si
• Molecular weight: 360.6055
• IUPAC Standard InChI: InChI=1S/C22H36O2Si/c1-21-12-10-16(24-25(3,4)5)14-15(21)6-7-17-18-8-9-20(23)22(18,2)13-11-19(17)21/h6,16-19H,7-14H2,1-5H3/t16-,17?,18?,19?,21?,22?/m1/s1 Copy

  
• IUPAC Standard InChIKey: BVHPVDOXVFBYNL-OWXTWKKPSA-N Copy
• CAS Registry Number: 3747-91-9
• Chemical structure:
  This structure is also available as a 2d Mol file
• Stereoisomers:
  • 5-Androsten-3-α-ol-17-one, TMS
  • Dehydroepiandrosterone, (E)-, TMS derivative
• Other names: Androst-5-en-17-one, 3-[(trimethylsilyl)oxy]-, (3β)-; Androst-5-en-17-one, 3β-(trimethylsiloxy)-; Androst-5-en-3β-ol-17-one, TMS; Dehydroepiandrosterone, TMS; Dehydroepiandrosterone, TMSi (3-O); Androsterone, mono-TMS
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• Information on this page:
  • Kovats' RI, non-polar column, isothermal
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Options:
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Kovats' RI, non-polar column, isothermal

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quilliam and Westmore, 1978
Quilliam, M.A.; Westmore, J.B., Sterically crowded trialkylsilyl derivatives for chromatography and mass spectrometry of biologically-important compounds, Anal. Chem., 1978, 50, 1, 59-68, https://doi.org/10.1021/ac50023a020 . [all data]

Voelter, Jung, et al., 1971
Voelter, W.; Jung, G.; Breitmaier, E.; Bouchon, G.; Bayer, E.; Gupta, D., Comparison of the trifluoroacetyl and trimethylsilylether derivaties for gas chromatography of steroids, Anal. Chim. Acta., 1971, 53, 1, 185-188, https://doi.org/10.1016/S0003-2670(01)80085-4 . [all data]

Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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