Homovanillic Acid, 2TMS derivative


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5DB-5CP Sil 5 CB
Column length (m) 30.30.30.30.25.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.15
Phase thickness (μm) 0.250.250.250.250.12
Tstart (C) 50.50.50.50.90.
Tend (C) 240.240.240.240.270.
Heat rate (K/min) 3.3.7.7.10.
Initial hold (min)     1.
Final hold (min)     7.
I 1785.1792.1785.1791.1760.
ReferenceJaroszynska, 2003Jaroszynska, 2003Jaroszynska, 2003Jaroszynska, 2003Halket, Przyborowska, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1OV-1SE-52CP Sil 5 CB
Column length (m) 30.30.10.25. 
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.530.220.32 
Phase thickness (μm) 1.1.0.170.52 
Tstart (C) 100.70.70.70.60.
Tend (C) 290.290.270.270.280.
Heat rate (K/min) 4.4.5.5.6.
Initial hold (min) 4.   0.5
Final hold (min) 10.   5.
I 1783.1757.1756.1785.1758.
ReferenceKimura, Yamamoto, et al., 1999Hoffmann, Aramaki, et al., 1989Lefevere, Verhaeghe, et al., 1989Lefevere, Verhaeghe, et al., 1989Wurth, Kumps, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPackedPacked
Active phase Ultra-2OV-1OV-1OV-1
Column length (m) 25.1.82.2.
Carrier gas HeN2N2He
Substrate  100-120 meshSupelcoportChromosorb W HP (80-100 mesh)
Column diameter (mm) 0.31   
Phase thickness (μm) 0.52   
Tstart (C) 50.70.80.100.
Tend (C) 300.290.240.325.
Heat rate (K/min) 5.28.4.10.
Initial hold (min)  0.5  
Final hold (min)     
I 1786.1758.1761.1758.
ReferenceTuchman, Bowers, et al., 1984Tanaka, Hine, et al., 1980Mattsson and Petersson, 1977Butts, 1972
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jaroszynska, 2003
Jaroszynska, J., Isolation of free phenolic compounds from arboreal leaves by use of the Florisil/C18 system, Anal. Bioanal. Chem., 2003, 377, 4, 702-708, https://doi.org/10.1007/s00216-003-2155-z . [all data]

Halket, Przyborowska, et al., 1999
Halket, J.N.; Przyborowska, A.; Stein, S.E.; Mallard, W.G.; Down, S.; Chalmers, R., Deconvolution gas chromatography / mass spectrometry of urinary organic acids - potential for pattern recognition and automated identification of metabolic disorders, Rapid Commun. Mass spectrom., 1999, 13, 4, 279-284, https://doi.org/10.1002/(SICI)1097-0231(19990228)13:4<279::AID-RCM478>3.0.CO;2-I . [all data]

Kimura, Yamamoto, et al., 1999
Kimura, M.; Yamamoto, T.; Yamaguchi, S., Automated metabolic profiling and interpretation of GC/MS data for organic acidemia screening: a personal computer-based system, Tohoku J. Exp. Med., 1999, 188, 4, 317-334, https://doi.org/10.1620/tjem.188.317 . [all data]

Hoffmann, Aramaki, et al., 1989
Hoffmann, G.; Aramaki, S.; Blum-Hoffmann, E.; Nyhan, W.L.; Sweetman, L., Quantitative analysis for organic acids in biological samples: batch isolation followed by gas chromatographic-mass spectrometric analysis, Clin. Chem., 1989, 35, 4, 587-595. [all data]

Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M., Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography, J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23 . [all data]

Wurth, Kumps, et al., 1989
Wurth, C.; Kumps, A.; Mardens, Y., Urinary organic acids: Retention indices on two capillary gas chromatography columns, J. Chromatogr., 1989, 491, 186-192, https://doi.org/10.1016/S0378-4347(00)82831-5 . [all data]

Tuchman, Bowers, et al., 1984
Tuchman, M.; Bowers, L.D.; Fregien, K.D.; Crippin, P.J.; Krivit, W., Capillary Gas Chromatographic Separation of Urinary Organic Acids. Retention Indices of 101 Urinary Acids on a 5% Phenylmethyl Silicone Capillary Column, J. Chromatogr. Sci., 1984, 22, 5, 198-202, https://doi.org/10.1093/chromsci/22.5.198 . [all data]

Tanaka, Hine, et al., 1980
Tanaka, K.; Hine, D.G.; West-Dull, A.; Lynn, T.B., Gas-chromatographic method of analysis for urinary organic acids. I. Retention indices of 155 metabolically important compounds, Clin. Chem., 1980, 26, 13, 1839-1846. [all data]

Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G., Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives, J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]


Notes

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