Nickel acetylacetonate
- Formula: C10H14NiO4
- Molecular weight: 256.9092
- IUPAC Standard InChI: InChI=1S/2C5H8O2.Ni/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
- IUPAC Standard InChIKey: BMGNSKKZFQMGDH-FDGPNNRMSA-L
- CAS Registry Number: 3264-82-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Nickel, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-; Nickel, bis(2,4-pentanedionato)-; Acetylacetonato nickel; Bis(acetylacetonate)nickel; Bis(acetylacetonato)nickel; Bis(2,4-pentanedionato)nickel; Bis-2,4-pentanedionatonickel(II); Ni(II) Acetylacetone complex (1:2); Nickel acetonylacetonate; Nickel bis(acetylacetonate); Nickel bis(2,4-pentanedionate); Nickel(II) acetylacetonate; Nickel(2+) acetylacetonate; Nickelous acetylacetonate; Nickel(II) 2,4-pentanedionate; Bis(acetylacetonato)nickel(II); Acetylacetonatonickel (II); Bis(acetylacetone)nickel; NSC 4657; bis(pentane-2,4-dionato-O,O')nickel
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.23 ± 0.05 | EI | Reichert and Westmore, 1969 | RDSH |
| 7.62 | PE | Kitagawa, Morishima, et al., 1983 | Vertical value; LBLHLM |
| 7.35 | PE | Fragala, Costanzo, et al., 1980 | Vertical value; LLK |
| 7.40 | PE | Cauletti, Furlani, et al., 1980 | Vertical value; LLK |
| 7.41 | PE | Cauletti and Furlani, 1975 | Vertical value; LLK |
| 7.61 | PE | Brittain and Disch, 1975 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C5H7O2Ni+ | 13.5 ± 0.2 | ? | EI | Reichert and Westmore, 1969 | RDSH |
| C9H11O4Ni+ | 11.6 ± 0.1 | ? | EI | Reichert and Westmore, 1969 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reichert and Westmore, 1969
Reichert, C.; Westmore, J.B.,
Mass spectral studies of metal chelates. IV.Mass spectra, appearance potentials, and coordinate bond energies of bis(acetylacetonate)metal(II) complexes of the first transition series,
Inorg. Chem., 1969, 8, 1012. [all data]
Kitagawa, Morishima, et al., 1983
Kitagawa, S.; Morishima, I.; Yoshikawa, K.,
UV photoelectron spectra of some transition metal(II)aAcetylacetonates,
Polyhedron, 1983, 2, 43. [all data]
Fragala, Costanzo, et al., 1980
Fragala, I.; Costanzo, L.L.; Ciliberto, E.; Condorelli, G.; D'Arrigo, C.,
He-I and He-II excited photoelectron spectra of tetracoordinated complexes of transition metal ions with β-diketonate ligands,
Inorg. Chim. Acta, 1980, 40, 15. [all data]
Cauletti, Furlani, et al., 1980
Cauletti, C.; Furlani, C.; Storto, G.,
Coordinative bond d-shell ionisations in the UV photoelectron spectra of bis({beta}-diketonato) cobalt (II) copper (II) complexes, their thio analogues,
J. Electron Spectrosc. Relat. Phenom., 1980, 18, 329. [all data]
Cauletti and Furlani, 1975
Cauletti, C.; Furlani, C.,
He(I) photoelectron spectra of bis(β-diketonate)nickel(II) complexes their and mono- and di-thio analogues,
J. Electron Spectrosc. Relat. Phenom., 1975, 6, 465. [all data]
Brittain and Disch, 1975
Brittain, H.G.; Disch, R.L.,
The He(I) photoelectron spectra of some bivalent transition metal β-diketonate complexes*,
J. Electron Spectrosc. Relat. Phenom., 1975, 7, 475. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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