Cyclopentadienylmanganesedicarbonylthiocarbonyl
- Formula: C8H5MnO2S
- Molecular weight: 220.127
- IUPAC Standard InChI: InChI=1S/C5H5.2CO.CS.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;
- IUPAC Standard InChIKey: ARWWINMOAIYYIT-UHFFFAOYSA-N
- CAS Registry Number: 31741-76-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Manganese,(carbonothioyl)dicarbonyl(η5-2,4-cyclopentadien-1-yl
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.78 ± 0.01 | EI | Efraty, Huang, et al., 1975 | |
| 7.81 | PE | Lichtenberger and Fenske, 1976 | Vertical value |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C5H5Mn+ | 12.25 ± 0.03 | 2CO+CS | EI | Efraty, Huang, et al., 1975 | |
| C5H9O2F9SiP3Mn+ | 16.91 ± 0.02 | 2CO+C5H5 | EI | Efraty, Huang, et al., 1975 | |
| C6H5SMn+ | 9.25 ± 0.01 | 2CO | EI | Efraty, Huang, et al., 1975 | |
| C7H5OSMn+ | 8.18 ± 0.01 | CO | EI | Efraty, Huang, et al., 1975 | |
| Mn+ | 16.51 ± 0.04 | 2CO+CS+C5H | EI | Efraty, Huang, et al., 1975 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Efraty, Huang, et al., 1975
Efraty, A.; Huang, M.H.A.; Weston, C.A.,
Mass spectra of organometallic compounds. V. Electron-impact study of the cyclopentadienylmanganese thiocarbonyl and carbonyl complexes RC5H4Mn(CO)2CX [R=H, CH3; X = S, O],
Inorg. Chem., 1975, 14, 2796. [all data]
Lichtenberger and Fenske, 1976
Lichtenberger, D.L.; Fenske, R.F.,
Electronic structure of transition metal thiocarbonyl complexes,
Inorg. Chem., 1976, 15, 2015. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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