2-Cyclohexen-1-ol, 1-methyl-4-(1-methylethyl)-, trans-


Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1-MSSPB-5HP-5SLB-5 MSZB-1
Column length (m) 60.60.30.30.30.
Carrier gas HeliumNitrogenHeliumHeliumNitrogen
Substrate      
Column diameter (mm) 0.250.350.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 30.60.40.50.45.
Tend (C) 200.230.240.250.230.
Heat rate (K/min) 2.4.4.3.3.
Initial hold (min) 4. 4.2. 
Final hold (min) 35.40. 10. 
I 1108.1145.1145.1124.1116.
ReferenceTakeoka, Hobbs, et al., 2010Gauvin-Bialecki and Marodon, 2009Zhannan, Shiqiong, et al., 2009Lo Presti, Sciarrone, et al., 2008Mierendorff, Stahl-Biskup, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5DB-5MSCol-Elite 5MSDB-1
Column length (m) 30.30.30.30.30.
Carrier gas HeliumN2HeHeHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.50.60.30.50.
Tend (C) 230.240.240.246.260.
Heat rate (K/min) 3.5.3.3.2.5
Initial hold (min) 10.1.  1.
Final hold (min) 10.4.  20.
I 1140.1140.1141.1139.1099.
ReferenceAdams, Beauchamp, et al., 2007Cheraif, Ben Jannet, et al., 2007Da Silva J.K.R., Sousa P.J.C., et al., 2007Gudaityte and Venskutonis R.P., 2007Monser-Esfahani, Karamkhani, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5SPB-1BP-1HP-5
Column length (m) 30.30.30.50.30.
Carrier gas N2N2HeliumHeHe
Substrate      
Column diameter (mm) 0.250.250.200.220.25
Phase thickness (μm) 0.250.250.200.250.25
Tstart (C) 50.50.70.60.50.
Tend (C) 280.280.220.220.300.
Heat rate (K/min) 9.9.3.2.5.
Initial hold (min) 3.3.  5.
Final hold (min) 3.3.15.20.5.
I 1120.1123.1120.1123.1152.
ReferenceAbdelwahed, Hayder, et al., 2006Abdelwahed, Hayder, et al., 2006Cavaleiro, Pinto, et al., 2006Fanciullino, Tomi, et al., 2006Figuérédo, Cabassu, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBSE-52DB-1DB-5DB-1
Column length (m) 30.50.50.30.60.
Carrier gas N2HeliumN2HeHelium
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.25 0.250.250.25
Tstart (C) 50.50.95.60.60.
Tend (C) 300.240.240.200.250.
Heat rate (K/min) 4.3.4.2.5.
Initial hold (min)      
Final hold (min)    60.10.
I 1101.1141.1132.1147.1126.
ReferenceLis and Milczarek, 2006Ozcan, Chalchat, et al., 2006Pala-Paul J., Perez-Alonso M.J., et al., 2006Rout, Naik, et al., 2006Sonboli, Mirjalili, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5RSL-200HP-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 60.50.40.70.40.
Tend (C) 240.300.280.240.240.
Heat rate (K/min) 3.5.6.5.4.
Initial hold (min)  5.2.  
Final hold (min)  5.10.  
I 1146.1152.1122.1140.1140.
ReferenceChaverri and Cicció, 2005Figuérédo, Cabassu, et al., 2005Jirovetz, Buchbauer, et al., 2005Oyedeji, Yani, et al., 2005Sefidkon and Jamzad, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSPE-5DB-1DB-5SE-54
Column length (m) 30.30.60.30.30.
Carrier gas HeH2HeN2He
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.40.60.
Tend (C) 280.230.250.230.260.
Heat rate (K/min) 3.5.5.2.2.
Initial hold (min) 5.2.  5.
Final hold (min)  4.10.  
I 1139.1114.1111.1140.1118.
ReferenceSetzer, Noletto, et al., 2005Singh, Raina, et al., 2005Sonboli, Salehi, et al., 2005González, Guerra, et al., 2004Kilic, Hafizoglu, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1DB-5HP-1DB-5DB-5
Column length (m) 30.30.30.30.60.
Carrier gas N2 HeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.32
Phase thickness (μm) 0.250.250.330.25 
Tstart (C) 60.50.40.60.50.
Tend (C) 300.250.260.240.200.
Heat rate (K/min) 4.3.2.3.3.
Initial hold (min)  5.5.  
Final hold (min)   20.  
I 1098.1140.1083.1138.1128.
ReferenceLis, Boczek, et al., 2004Sefidkon, Jamzad, et al., 2004Senatore, Napolitano, et al., 2004Tellez, Khan, et al., 2004Edris, Shalaby, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5ZB-1HP-5DB-5DB-1
Column length (m) 50.30.30.30.60.
Carrier gas HeN2HeliumH2He
Substrate      
Column diameter (mm) 0.20.250.320.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 50.45.70.60.50.
Tend (C) 220.230.210.280.280.
Heat rate (K/min) 3.3.2.4.4.
Initial hold (min) 2.  10. 
Final hold (min)   60.40. 
I 1141.1116.1141.1142.1126.
ReferenceMasotti, Juteau, et al., 2003Mierendorff, Stahl-Biskup, et al., 2003Mookdasanit, Tamura, et al., 2003Pino, Marbot, et al., 2003Shahmir, Ahmadi, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-15 % Phenyl methyl siloxaneDB-5MSHP-5
Column length (m) 25.30.30.30.30.
Carrier gas N2HeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.70.75.60.60.
Tend (C) 250.220.200.240.240.
Heat rate (K/min) 4.3.3.3.3.
Initial hold (min)   4.  
Final hold (min) 10.15.8.  
I 1097.1120.1141.1137.1143.
ReferenceZrira, Elamrani, et al., 2003Cavaleiro, Salgueiro, et al., 2002Cicció and Gómez-Laurito, 2002Maia, Zoghbi, et al., 2002Novak, Langbehn, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5BP-1OV-101OV-101OV-101
Column length (m) 30.50.50.50.50.
Carrier gas  HeN2N2N2
Substrate      
Column diameter (mm) 0.250.220.250.250.25
Phase thickness (μm) 0.250.25   
Tstart (C) 60.60.80.80.80.
Tend (C) 240.230.200.200.200.
Heat rate (K/min) 3.2.2.2.2.
Initial hold (min)      
Final hold (min)  35.   
I 1146.1123.1112.1110.1112.
ReferenceNovak, Langbehn, et al., 2002Lota, de Rocca Serra, et al., 2001Yang, 2001Yang, 2001, 2Yang, 2001, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1DB-5MSOV-101HP-5HP-5
Column length (m) 30.30.50.  
Carrier gas N2HeN2  
Substrate      
Column diameter (mm) 0.250.250.25  
Phase thickness (μm) 0.250.250.17  
Tstart (C) 60.60.50.40.40.
Tend (C) 300.240.220.210.210.
Heat rate (K/min) 4.3.5.2.2.
Initial hold (min)      
Final hold (min)      
I 1111.1143.1120.1106.1106.
ReferenceKalemba, 1999Zoghbi, Andrade, et al., 1999Chacko, Jayalekshmy, et al., 1996Collin, Deslauriers, et al., 1993Collin, Deslauriers, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Methyl SiliconeMethyl SiliconeOV-101OV-101BP-1
Column length (m) 50.50.50.50.25.
Carrier gas N2N2   
Substrate      
Column diameter (mm) 0.250.250.250.250.33
Phase thickness (μm) 0.170.17   
Tstart (C) 80.80.80.80.45.
Tend (C) 200.200.200.200.180.
Heat rate (K/min) 2.3.2.2.3.
Initial hold (min)     3.
Final hold (min)      
I 1128.1128.1111.1112.1121.
ReferenceGopalakrishnan, Menon, et al., 1993Gopalakrishnan, Menon, et al., 1993Tamura, Yang, et al., 1993Tamura, Yang, et al., 1993Wyllie, Brophy, et al., 1990
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101BP-1OV-101OV-101
Column length (m) 50.50.50.50.50.
Carrier gas N2N2H2  
Substrate      
Column diameter (mm) 0.250.250.300.300.30
Phase thickness (μm)      
Tstart (C) 80.80.40.40.40.
Tend (C) 200.200.250.230.230.
Heat rate (K/min) 2.2.10.3.53.5
Initial hold (min)   1.5.5.
Final hold (min)      
I 1111.1112.1112.1104.1125.
ReferenceYang and Sugisawa, 1990Yang and Sugisawa, 1990Brophy, Davies, et al., 1989Nykanen, 1986Nykanen, 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Takeoka, G.R.; Hobbs, C.; Byeoung-Soo, P., Volatile constituents of the aerial parts of Salvia apiana Jepson, J. Essential Oil. Res., 2010, 22, 3, 241-244, https://doi.org/10.1080/10412905.2010.9700314 . [all data]

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Tellez, Khan, et al., 2004
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Edris, Shalaby, et al., 2003
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Masotti, Juteau, et al., 2003
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Mierendorff, Stahl-Biskup, et al., 2003
Mierendorff, H.-G.; Stahl-Biskup, E.; Posthumus, M.A.; van Beek, T.A., Composition of commercial Cape chamomile oil (Eriocephalus punctulatus), Flavour Fragr. J., 2003, 18, 6, 510-514, https://doi.org/10.1002/ffj.1259 . [all data]

Mookdasanit, Tamura, et al., 2003
Mookdasanit, J.; Tamura, H.; Yoshizawa T.; Tokunaga T.; Nakanishi, K., Trace Volatile Compounds in Essential Oil of Citrus Sudachi by Means of Modified Solvent Extraction Method, Food Sci Technol. Res., 2003, 9, 1, 54-61, https://doi.org/10.3136/fstr.9.54 . [all data]

Pino, Marbot, et al., 2003
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Notes

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