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Cyclodecane

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Hydrogen + Cyclodecyne = Cyclodecane

By formula: 2H2 + C10H16 = C10H20

Quantity Value Units Method Reference Comment
Deltar-236.2 ± 0.96kJ/molChydTurner, Jarrett, et al., 1973liquid phase; solvent: Acetic acid
Deltar-236.kJ/molChydSicher, Svoboda, et al., 1966liquid phase; solvent: Acetic acid

2Hydrogen + trans,trans-1,6-Cyclodecadiene = Cyclodecane

By formula: 2H2 + C10H16 = C10H20

Quantity Value Units Method Reference Comment
Deltar-199.3kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

cis,cis-1,6-Cyclodecadiene + 2Hydrogen = Cyclodecane

By formula: C10H16 + 2H2 = C10H20

Quantity Value Units Method Reference Comment
Deltar-183.0kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

Hydrogen + Cyclodecene, (Z)- = Cyclodecane

By formula: H2 + C10H18 = C10H20

Quantity Value Units Method Reference Comment
Deltar-86.5 ± 0.3kJ/molChydTurner and Meador, 1957liquid phase; solvent: Acetic acid

Hydrogen + Cyclodecene, (E)- = Cyclodecane

By formula: H2 + C10H18 = C10H20

Quantity Value Units Method Reference Comment
Deltar-100. ± 4.kJ/molChydTurner and Meador, 1957liquid phase; solvent: Acetic acid

4Hydrogen + Meso 1,2,6,7-cyclodecatetraene = Cyclodecane

By formula: 4H2 + C10H12 = C10H20

Quantity Value Units Method Reference Comment
Deltar-514.6 ± 0.8kJ/molChydRoth, Adamczak, et al., 1991liquid phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Turner, Jarrett, et al., 1973
Turner, R.B.; Jarrett, A.D.; Goebel, P.; Mallon, B.J., Heats of hydrogenation. 9. Cyclic acetylenes and some miscellaneous olefins, J. Am. Chem. Soc., 1973, 95, 790-792. [all data]

Sicher, Svoboda, et al., 1966
Sicher, J.; Svoboda, M.; Zavada, J.; Turner, R.B.; Goebel, P., Sterochemical studies - XXXVI. An approach to conformational analysis of medium ring compounds. Unsaturated ten-membered ring derivates, Tetrahedron, 1966, 22, 659-671. [all data]

Turner, Mallon, et al., 1973
Turner, R.B.; Mallon, B.J.; Tichy, M.; Doering, W.v.E.; Roth, W.R.; Schroder, G., Heats of hydrogenation. X. Conjugative interaction in cyclic dienes and trienes, J. Am. Chem. Soc., 1973, 95, 8605-8610. [all data]

Turner and Meador, 1957
Turner, R.B.; Meador, W.R., Heats of hydrogenation. IV. Hydrogenation of some cis- and trans-cycloolefins, J. Am. Chem. Soc., 1957, 79, 4133-4136. [all data]

Roth, Adamczak, et al., 1991
Roth, W.R.; Adamczak, O.; Breuckmann, R.; Lennartz, H.-W.; Boese, R., Die Berechnung von Resonanzenergien; das MM2ERW-Kraftfeld, Chem. Ber., 1991, 124, 2499-2521. [all data]


Notes

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