Thietane

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C3H6S+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)8.61eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)199.5kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity192.4kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.61PIPECOButler and Baer, 1983LBLHLM
8.5PEAue and Bowers, 1979LLK
8.65 ± 0.01PITrofimov, Mel'der, et al., 1975LLK
8.65SWhiteside and Warsop, 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHS+10.5 ± 0.1C2H5PIButler and Baer, 1982T = 0K; LBLHLM
CHS+10.4 ± 0.1C2H5PIButler and Baer, 1982T = 298K; LBLHLM
CHS+13.9 ± 0.2?EIGallegos and Kiser, 1962RDSH
CH2S+9.9C2H4PIPECOButler and Baer, 1983LBLHLM
CH2S+10.4 ± 0.1?EIJones and Lossing, 1967RDSH
CH3S+12.3 ± 0.15?EIGallegos and Kiser, 1962RDSH
C2H2+17.1 ± 0.4?EIGallegos and Kiser, 1962RDSH
C2H3+16.7 ± 0.2?EIGallegos and Kiser, 1962RDSH
C2H3S+10.0CH3PIPECOButler and Baer, 1983LBLHLM
C2H4+13.6 ± 0.2?EIGallegos and Kiser, 1962RDSH
C3H3+15.3 ± 0.4?EIGallegos and Kiser, 1962RDSH
C3H5+12.2 ± 0.2SH?EIGallegos and Kiser, 1962RDSH
C3H5S+10.8HPIPECOButler and Baer, 1983LBLHLM

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Butler and Baer, 1983
Butler, J.J.; Baer, T., A photoionization study of organosulfur ring compounds: Thiirane, thietane and tetrahydrothiophene, Org. Mass Spectrom., 1983, 18, 248. [all data]

Aue and Bowers, 1979
Aue, D.H.; Bowers, M.T., Chapter 9. Stabilities of positive ions from equilibrium gas phase basicity measurements in Ions Chemistry,, ed. M.T. Bowers, 1979. [all data]

Trofimov, Mel'der, et al., 1975
Trofimov, B.A.; Mel'der, U.K.; Pikver, R.I.; Vyalykh, E.P., Ionization potentials of unsaturated and sulfides the participation of neighboring multiple bonds of heteroatoms in the stabilization of the radical cation, Teor. Eksp. Khim., 1975, 11, 129. [all data]

Whiteside and Warsop, 1969
Whiteside, J.A.B.; Warsop, P.A., The electronic spectrum of trimethylene sulfide, J. Mol. Spectry., 1969, 29, 1. [all data]

Butler and Baer, 1982
Butler, J.J.; Baer, T., Photoionization study of the heat of formation of HCS+, J. Am. Chem. Soc., 1982, 104, 5016. [all data]

Gallegos and Kiser, 1962
Gallegos, E.J.; Kiser, R.W., Electron impact spectroscopy of the four- and five-membered, saturated heterocyclic compounds containing nitrogen, oxygen and sulfur, J. Phys. Chem., 1962, 66, 136. [all data]

Jones and Lossing, 1967
Jones, A.; Lossing, F.P., The ionization potential and heat of formation of thioformaldehyde, J. Phys. Chem., 1967, 71, 4111. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References