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Bicyclo[3.1.0]hexane

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C6H10+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.28 ± 0.05EIWolkoff and Holmes, 1979LLK
9.16 ± 0.02EIWinters and Collins, 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H3+12.98 ± 0.19?EIWinters and Collins, 1969RDSH
C3H5+11.65 ± 0.14?EIWinters and Collins, 1969RDSH
C4H5+12.62 ± 0.11?EIWinters and Collins, 1969RDSH
C4H6+10.28 ± 0.05?EIWinters and Collins, 1969RDSH
C5H5+13.20 ± 0.12?EIWinters and Collins, 1969RDSH
C5H7+9.88 ± 0.05CH3EIWolkoff and Holmes, 1979LLK
C5H7+9.68 ± 0.07CH3EIWinters and Collins, 1969RDSH
C6H7+11.60 ± 0.15H2+HEIWinters and Collins, 1969RDSH
C6H9+10.20 ± 0.10HEIWinters and Collins, 1969RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wolkoff and Holmes, 1979
Wolkoff, P.; Holmes, J.L., Isomeric cyclic [C6H10]+ ions. The energy barrier to ring opening, Can. J. Chem., 1979, 57, 348. [all data]

Winters and Collins, 1969
Winters, R.E.; Collins, J.H., Mass spectrometric studies of structural isomers. II.Mono- and bicyclic C6H10 molecules, Org. Mass Spectrom., 1969, 2, 299. [all data]


Notes

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