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Bicyclo[2.2.2]octane

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2Hydrogen + Bicyclo[2.2.2]octa-2,5-diene = Bicyclo[2.2.2]octane

By formula: 2H2 + C8H10 = C8H14

Quantity Value Units Method Reference Comment
Deltar-235.2 ± 0.42kJ/molChydTurner, Meador, et al., 1957liquid phase; solvent: Acetic acid

Hydrogen + Bicyclo[2.2.2]oct-2-ene = Bicyclo[2.2.2]octane

By formula: H2 + C8H12 = C8H14

Quantity Value Units Method Reference Comment
Deltar-118.2 ± 0.84kJ/molChydTurner, Meador, et al., 1957liquid phase; solvent: Acetic acid

3Hydrogen + Bicyclo[2.2.2]octa-2,5,7-triene = Bicyclo[2.2.2]octane

By formula: 3H2 + C8H8 = C8H14

Quantity Value Units Method Reference Comment
Deltar-392.4 ± 1.3kJ/molChydTurner, 1964liquid phase; solvent: Acetic acid

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Turner, Meador, et al., 1957
Turner, R.B.; Meador, W.R.; Winkler, R.E., Heats of hydrogenation. I. Apparatus and the heats of hydrogenation of bicyclo[2,2,1]heptene, bicyclo[2,2,1]heptadiene, bicyclo[2,2,2]octene and bicyclo[2,2,2]octadiene, J. Am. Chem. Soc., 1957, 79, 4116-4121. [all data]

Turner, 1964
Turner, R.B., Heat of Hydrogenation of Bicyclo[2.2.2]octa-2,5,7-triene, J. Am. Chem. Soc., 1964, 86, 3586-3587. [all data]


Notes

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