(1S,2E,6E,10R)-3,7,11,11-Tetramethylbicyclo[8.1.0]undeca-2,6-diene
- Formula: C15H24
- Molecular weight: 204.3511
- IUPAC Standard InChIKey: VPDZRSSKICPUEY-BFPRWLMKSA-N
- CAS Registry Number: 24703-35-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: Bicyclo[8.1.0]undeca-2,6-diene, 3,7,11,11-tetramethyl-, (1S,2E,6E,10R)-; Bicyclo[8.1.0]undeca-2,6-diene, 3,7,11,11-tetramethyl-, (E,E)-(1S,10R)-(+)-; Bicyclo[8.1.0]undeca-2,6-diene, 3,7,11,11-tetramethyl-, [1S-(1R*,2E,6E,10S*)]-; (+)-Bicyclogermacrene; Bicyclogermacren; Bicyclogermacrene; β-Cyclogermacrane; Bicylogermacrene
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
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Kovats' RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5MS | HP-5MS | HP-5MS | DB-5MS | HP-1 |
Column length (m) | 30. | 30. | 60. | 30. | 60. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 40. | 60. | 60. |
Tend (C) | 180. | 280. | 250. | 280. | 200. |
Heat rate (K/min) | 3. | 2. | 3. | 3. | 4. |
Initial hold (min) | 8. | 1. | 5. | ||
Final hold (min) | 15. | 30. | 20. | 30. | 25. |
I | 1488. | 1495. | 1518. | 1470. | 1502. |
Reference | Angioni, Barra, et al., 2006 | Hazzit, Baaliouamer, et al., 2006 | Jalali-Heravi, Zekavat, et al., 2006 | Marongiu, Porcedda, et al., 2006 | Meccia G., Rosquete C., et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | DB-5 | HP-5MS | HP-5MS | BP-5 |
Column length (m) | 25. | 30. | 30. | 30. | 50. |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.2 | 0.25 | 0.25 | 0.25 | 0.32 |
Phase thickness (μm) | 0.33 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 40. | 50. | 50. | 50. |
Tend (C) | 240. | 210. | 240. | 250. | 260. |
Heat rate (K/min) | 3. | 2. | 3. | 3. | 5. |
Initial hold (min) | 2. | 10. | 2. | ||
Final hold (min) | 33. | 5. | 5. | ||
I | 1495. | 1496. | 1533. | 1498. | 1499. |
Reference | Oliveira, Leitao, et al., 2006 | Sylvestre, Pichette, et al., 2006 | Tepe, Askin Akpulat, et al., 2006 | Asuming, Beauchamp, et al., 2005 | Baranauskiene, Venskutonis, et al., 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5MS | DB-5 | HP-5MS | HP-5MS | DB-1 |
Column length (m) | 30. | 30. | 30. | 30. | 50. |
Carrier gas | He | He | He | He | N2 |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.32 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 70. | 70. | 95. |
Tend (C) | 240. | 300. | 250. | 250. | 240. |
Heat rate (K/min) | 3. | 5. | 3. | 3. | 4. |
Initial hold (min) | 5. | 5. | |||
Final hold (min) | |||||
I | 1495. | 1486. | 1486. | 1501. | 1492. |
Reference | Maia, Andrade, et al., 2005 | Santos, Lopes, et al., 2004 | Siani, Garrido, et al., 2004 | Siani, Garrido, et al., 2004 | Velasco-Negueruela, Sanz, et al., 2004 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP Sil 5 CB | DB-5 | HP-5 | BP-1 | DB-5 |
Column length (m) | 25. | 25. | 30. | 30. | 30. |
Carrier gas | H2 | He | He | N2 | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.22 | 0.25 | 0.32 | 0.26 |
Phase thickness (μm) | 0.15 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 50. | 60. | 60. | 60. | 60. |
Tend (C) | 230. | 240. | 200. | 220. | 240. |
Heat rate (K/min) | 3. | 3. | 4. | 5. | 3. |
Initial hold (min) | 1. | ||||
Final hold (min) | 15. | 13. | |||
I | 1497. | 1480. | 1496. | 1486. | 1494. |
Reference | Ogunwande, Olawore, et al., 2003 | El-Ghorab, Fadel, et al., 2002 | Juliani and Simon, 2002 | Shawl, Srivastava, et al., 2002 | Adams, 2000 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | BP-5 | DB-5 | CP Sil 5 CB | DB-5 |
Column length (m) | 25. | 25. | 30. | 25. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.22 | 0.25 | 0.26 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 70. | 60. | 60. | 60. | 60. |
Tend (C) | 220. | 200. | 246. | 280. | 240. |
Heat rate (K/min) | 5. | 3. | 3. | 5. | 3. |
Initial hold (min) | |||||
Final hold (min) | |||||
I | 1484. | 1497. | 1499. | 1494. | 1496. |
Reference | Kardali, Velasco-Negueruela, et al., 2000 | Weissbecker B., Van Loon J.J.A., et al., 2000 | Adams, 1999 | Kaul, Gujral, et al., 1999 | da Silva, Andrade, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | BP-1 | BP-1 | CP Sil 8 CB | DB-5 |
Column length (m) | 30. | 50. | 50. | 25. | 30. |
Carrier gas | He | Ar | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.15 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.12 | 0.25 |
Tstart (C) | 60. | 60. | 60. | 60. | 60. |
Tend (C) | 240. | 260. | 260. | 220. | 240. |
Heat rate (K/min) | 4. | 2. | 2. | 3. | 3. |
Initial hold (min) | |||||
Final hold (min) | |||||
I | 1497. | 1498. | 1500. | 1493. | 1495. |
Reference | da Silva, Zoghbi, et al., 1999 | Vera and Chane-Ming, 1999 | Vera and Chane-Ming, 1999 | Szafranek, Malinski, et al., 1998 | Tellez, Estell, et al., 1997 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|
Active phase | DB-5 | DB-5 | DB-5 | OV-101 |
Column length (m) | 30. | 30. | 30. | 25. |
Carrier gas | N2 | |||
Substrate | ||||
Column diameter (mm) | 0.25 | |||
Phase thickness (μm) | ||||
Tstart (C) | 40. | 40. | 40. | 50. |
Tend (C) | 210. | 210. | 210. | 200. |
Heat rate (K/min) | 2. | 2. | 2. | 5. |
Initial hold (min) | 2. | 2. | 2. | |
Final hold (min) | 120. | 120. | 120. | |
I | 1490. | 1497. | 1497. | 1496. |
Reference | Loayza, Abujder, et al., 1995 | Loayza, Abujder, et al., 1995 | Loayza, Abujder, et al., 1995 | Menut, Molangui, et al., 1995 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Angioni, Barra, et al., 2006
Angioni, A.; Barra, A.; Coroneo, V.; Dessi, S.; Cabras, P.,
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Composition of the Essential Oils of Thymus and Origanum Species from Algeria and Their Antioxidant and Antimicrobial Activities,
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Jalali-Heravi, Zekavat, et al., 2006
Jalali-Heravi, M.; Zekavat, B.; Sereshti, H.,
Characterization of essential oil components of Iranian geranium oil using gas chromatography-mass spectrometry combined with chemometric resolution techniques,
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Extraction of Juniperus communis L. ssp. nana Willd. essential oil by supercritical carbon dioxide,
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Oliveira, Leitao, et al., 2006
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Ethnopharmacological study of two Lippia species from Oriximina, Brazil,
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Sylvestre, Pichette, et al., 2006
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Essential oil analysis and anticancer activity of leaf essential oil of Croton flavens L. from Guadeloupe,
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Tepe, Askin Akpulat, et al., 2006
Tepe, B.; Askin Akpulat, H.; Sokmen, M.; Daferera, D.; Yumrutas, O.; Aydin, E.; Polissiou, M.; Sokmen, A.,
Screening of the antioxidative and antimicrobial properties of the essential oils of Pimpinella anisetum and Pimpinella flabellifolia from Turkey,
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Asuming, Beauchamp, et al., 2005
Asuming, W.A.; Beauchamp, P.S.; Descalzo, J.T.; Dev, B.C.; Dev, V.; Frost, S.; Ma, C.W.,
Essential oil composition of four Lomatium Raf. species and their chemotaxonomy,
Biochem. Syst. Ecol., 2005, 33, 1, 17-26, https://doi.org/10.1016/j.bse.2004.06.005
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Baranauskiene, Venskutonis, et al., 2005
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Sensory and instrumental evaluation of sweet marjoram (Origanum majorana L.) aroma,
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Maia, Andrade, et al., 2005
Maia, J.G.S.; Andrade, E.H.A.; da Silva, A.C.M.; Oliveira, J.; Carreira, L.M.M.; Araújo, J.S.,
Leaf volatile oils from four Brazilian Xylopia species,
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Santos, Lopes, et al., 2004
Santos, A.P.; Lopes, M.C.; Limberger, R.P.; Apel, M.A.; Henriques, A.T.; Moreno, P.R.H.,
Analysis of the volatile oil from Pilocarpus pennatifolius Lemmaire (Rutaceae) leaves by GC-MS,
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Siani, Garrido, et al., 2004
Siani, A.C.; Garrido, I.S.; Monteiro, S.S.; Carvalho, E.S.; Ramos, M.F.S.,
Protium icicariba as a source of volatile essences,
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The volatile components of the aerial parts of Melittis melissophyllum L. subsp. melissophyllum gathered in Spain,
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Ogunwande, Olawore, et al., 2003
Ogunwande, I.A.; Olawore, N.O.; Kasali, A.A.; König, W.A.,
Chemical composition of the leaf volatile oils of Callitris intratropica R.T. Baker H.G. Smith from Nigeria,
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El-Ghorab, Fadel, et al., 2002
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The Egyptian Eucalyptus camaldulensis var. brevirostris: chemical compositions of the fruit volatile oil and antioxidant activity,
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Antioxidant acitivity of basil
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Shawl, Srivastava, et al., 2002
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Essential oil composition of Achillea millefolium L. growing wild in Kashmir, India,
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da Silva, Andrade, et al., 1999
da Silva, M.H.L.; Andrade, E.H.A.; Zoghbi, M.G.B.; Luz, A.I.R.; da Silva, J.D.; Maia, J.G.S.,
The essential oils of Lantana camara L. occurring in North Brazil,
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da Silva, Zoghbi, et al., 1999
da Silva, M.H.L.; Zoghbi, M.G.B.; Andrade, E.H.A.; Maia, J.G.S.,
The essential oils of Peperomia pellucida Kunth and P. circinnata link var. circinnata,
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Vera, R.R.; Chane-Ming, J.,
Chemical composition of the essential oil of marjoram (Origanum majorana L.) from Reunion Island,
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Szafranek, Malinski, et al., 1998
Szafranek, B.; Malinski, E.; Szafranek, J.,
The sesquiterpene composition of leaf cuticular neutral lipids of ten varieties of polish Solanum tuberosum,
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Essential oil of Dyssodia acerosa DC.,
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Menut, C.; Molangui, T.; Lamaty, G.E.; Bessière, J.-M.; Habimana, J.-B. Menut.; Molangui, T.; Lamaty, G.E.; Bessière, J.-M.; Habimana, J.-B.,
Aromatic plants of tropical Central Africa. 23. Chemical composition of leaf essential oils of Eucalyptus goniocalyx F. Muell. and Eucalyptus patens Benth. grown in Rwanda,
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. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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