Thiophosphoryl fluoride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + Thiophosphoryl fluoride = (Fluorine anion • Thiophosphoryl fluoride)

By formula: F- + F3PS = (F- • F3PS)

Quantity Value Units Method Reference Comment
Δr201. ± 38.kJ/molIMRBRhyne and Dillard, 1971gas phase; Fluoride Affinity: between SF4, SF5. Original value 32±10, now altered with new aff.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rhyne and Dillard, 1971
Rhyne, T.C.; Dillard, J.G., Reactions of gaseous inorganic negative ions: III. SF6- with POF3 and PSF3, Int. J. Mass Spectrom. Ion Phys., 1971, 7, 371. [all data]


Notes

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