Pyridine, 2-(1-methyl-2-pyrrolidinyl)-


Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedCapillaryCapillaryCapillaryCapillary
Active phase Polydimethyl siloxaneDB-5HP-5DB-1DB-5
Column length (m) 2.30.60.30.30.
Carrier gas Nitrogen HeHeH2
Substrate      
Column diameter (mm)  0.250.320.320.32
Phase thickness (μm)  0.250.25 1.
Tstart (C) 100.40.30.70.40.
Tend (C) 300.280.260.300.220.
Heat rate (K/min)  5.2.6.3.
Initial hold (min)   2.  
Final hold (min)  10.28.  
I 1346.1355.1366.51312.1379.
ReferenceMHA, 9999Grung, Lichtenthaler, et al., 2007Leffingwell and Alford, 2005Tofern, Kaloga, et al., 1999Moio, Dekimpe, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Ultra-1BP-1BP-1BP-1BP-1
Column length (m) 25.12.12.12.12.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.220.220.220.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 80.120.120.120.120.
Tend (C) 260.270.270.270.270.
Heat rate (K/min) 3.12.15.25.6.
Initial hold (min)      
Final hold (min)      
I 1307.1330.1332.1338.1324.
ReferenceOkumura, 1991Stowell and Wilson, 1985Stowell and Wilson, 1985Stowell and Wilson, 1985Stowell and Wilson, 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryPacked
Active phase BP-1BP-1BP-1BP-1SE-30
Column length (m) 12.12.12.12.2.
Carrier gas HeHeHeHe 
Substrate     Gas Chrom P
Column diameter (mm) 0.220.220.220.22 
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 120.100.120.50.120.
Tend (C) 270.295.280.300.200.
Heat rate (K/min) 8.5.8.20.2.5
Initial hold (min)      
Final hold (min)      
I 1328.1315.1326.1311.1340.
ReferenceStowell and Wilson, 1985Stowell and Wilson, 1985Stowell and Wilson, 1985Stowell and Wilson, 1985Marozzi, Gambaro, et al., 1982
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase SE-30SE-30SE-30SE-30SE-30
Column length (m) 2.2.2.2.2.
Carrier gas NitrogenNitrogenNitrogenNitrogenNitrogen
Substrate Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)
Column diameter (mm)      
Phase thickness (μm)      
Tstart (C) 130.130.130.130.130.
Tend (C) 290.290.290.290.290.
Heat rate (K/min) 8.8.8.8.8.
Initial hold (min) 2.2.2.2.2.
Final hold (min) 8.8.8.8.8.
I 1335.1325.1326.1327.1327.
ReferencePeel and Perrigo, 1976Peel and Perrigo, 1976Peel and Perrigo, 1976Peel and Perrigo, 1976Peel and Perrigo, 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPacked
Active phase SE-30SE-30SE-30
Column length (m) 2.2.2.
Carrier gas NitrogenNitrogenN2
Substrate Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS
Column diameter (mm)    
Phase thickness (μm)    
Tstart (C) 130.130.130.
Tend (C) 290.290.290.
Heat rate (K/min) 8.8.8.
Initial hold (min) 2.2.2.
Final hold (min) 8.8.8.
I 1329.1329.1335.
ReferencePeel and Perrigo, 1976Peel and Perrigo, 1976Peel and Perrigo, 1975
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

MHA, 9999
MHA, Directorate of ForensicScience., Forensic Toxicology, 9999. [all data]

Grung, Lichtenthaler, et al., 2007
Grung, M.; Lichtenthaler, R.; Ahel, M.; Tollefsen, K.-E.; Langford, K.; Thomas, K.V., Effects-directed analysis of organic toxicants in wastewater effluent from Zagreb, Croatia, Chemosphere, 2007, 67, 1, 108-120, https://doi.org/10.1016/j.chemosphere.2006.09.021 . [all data]

Leffingwell and Alford, 2005
Leffingwell, J.C.; Alford, E.D., Volatile constituents of Perique tobacco, Electron. J. Environ. Agric. Food Chem., 2005, 4, 2, 899-915. [all data]

Tofern, Kaloga, et al., 1999
Tofern, B.; Kaloga, M.; Witte, L.; Hartmann, T.; Eich, E., Occurrence of loline alkaloids in Argyreia mollis (Convolvulaceae), Phytochemistry, 1999, 51, 8, 1177-1180, https://doi.org/10.1016/S0031-9422(99)00121-1 . [all data]

Moio, Dekimpe, et al., 1993
Moio, L.; Dekimpe, J.; Etievant, P.; Addeo, F., Neutral volatile compounds in the raw milks from different species, J. Dairy Res., 1993, 60, 2, 199-213, https://doi.org/10.1017/S0022029900027515 . [all data]

Okumura, 1991
Okumura, T., retention indices of environmental chemicals on methyl silicone capillary column, Journal of Environmental Chemistry (Japan), 1991, 1, 2, 333-358, https://doi.org/10.5985/jec.1.333 . [all data]

Stowell and Wilson, 1985
Stowell, A.; Wilson, L., Use of retention indices in drug screening by capillary gas chromatography, Rep. # CD 2362, Department of Scientific and Industrial Reseach, Chemistry Division, Lower Hutt, NZ, 1985, 32. [all data]

Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F., Use of the retention index in gas chromatographic studies of drugs, J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185 . [all data]

Peel and Perrigo, 1976
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can. Soc. Forens. Sci. J., 1976, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]

Peel and Perrigo, 1975
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can.Soc.Forens.Sci.J., 1975, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]


Notes

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