Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Fluorenyl radical


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C13H9+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.869 ± 0.013LPDRömer, Janaway, et al., 1997B
1.81 ± 0.13D-EATaft and Bordwell, 1988B

Ionization energy determinations

IE (eV) Method Reference Comment
7.07EIPottie and Lossing, 1963RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Römer, Janaway, et al., 1997
Römer, B.; Janaway, G.; Brauman, J.I., Cyclopentadienyl, Indenyl, and Fluorenyl Anions: Gas-Phase and Solvation Energy Contributions to Electron Detachment Energies, J. Am. Chem. Soc., 1997, 119, 9, 2249, https://doi.org/10.1021/ja961947x . [all data]

Taft and Bordwell, 1988
Taft, R.W.; Bordwell, F.G., Structural and Solvent Effects Evaluated from Acidities Measured in Dimethyl Sulfoxide and in the Gas Phase, Acc. Chem. Res., 1988, 21, 12, 463, https://doi.org/10.1021/ar00156a005 . [all data]

Pottie and Lossing, 1963
Pottie, R.F.; Lossing, F.P., Free radicals by mass spectrometry. XXIX. Ionization potentials of substituted cyclopentadienyl radicals, J. Am. Chem. Soc., 1963, 85, 269. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References