Methanesulfonylacetonitrile


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C3H4NO2S- + Hydrogen cation = Methanesulfonylacetonitrile

By formula: C3H4NO2S- + H+ = C3H5NO2S

Quantity Value Units Method Reference Comment
Δr336.2 ± 2.3kcal/molG+TSTaft, Abboud, et al., 1988gas phase; Revised: this is 0.9 smaller than reported (91TAF)
Quantity Value Units Method Reference Comment
Δr328.6 ± 2.0kcal/molIMRETaft, Abboud, et al., 1988gas phase; Revised: this is 0.9 smaller than reported (91TAF)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft, Abboud, et al., 1988
Taft, R.W.; Abboud, J.L.M.; Anvia, F.; Berthelot, M.; Fujio, M.; Gal, J.-F.; Headley, A.D.; Henderson, W.G., Regarding the Inherent Dependence of Resonance Effects of Strongly Conjugated Substituents on Electron Demand, J. Am. Chem. Soc., 1988, 110, 6, 1797, https://doi.org/10.1021/ja00214a023 . [all data]


Notes

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