Cesium hydroxide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
Proton affinity (review)1117.9kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity1092.2kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
7.40 ± 0.15EIGorokhov, Gusarov, et al., 1970RDSH
7.21 ± 0.14EIEmel'yanov, Gusarov, et al., 1967RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cs+7.60 ± 0.15OHEIGorokhov, Gusarov, et al., 1970RDSH
Cs+7.46 ± 0.14OHEIEmel'yanov, Gusarov, et al., 1967RDSH
Cs+~10.OHEISchoonmaker and Porter, 1959RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Gorokhov, Gusarov, et al., 1970
Gorokhov, L.N.; Gusarov, A.V.; Panchenkov, I.G., Determination of dissociation energies of potassium and caesium hydroxides by electron bombardment, Zh. Fiz. Khim., 1970, 44, 269, In original 150. [all data]

Emel'yanov, Gusarov, et al., 1967
Emel'yanov, A.M.; Gusarov, A.V.; Gorokhov, L.N.; Sadovnikova, N.A., Electron-impact studies of the vapors of cesium oxide and hydroxide, Teor. i Eksperim, Khim., 1967, 3, 226, In original 126. [all data]

Schoonmaker and Porter, 1959
Schoonmaker, R.C.; Porter, R.F., Mass spectrometric study of alkali hydroxide vapors, J. Chem. Phys., 1959, 31, 830. [all data]


Notes

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