Benzenepropanoic acid, TMS derivative
- Formula: C12H18O2Si
- Molecular weight: 222.3556
- IUPAC Standard InChI: InChI=1S/C12H18O2Si/c1-15(2,3)14-12(13)10-9-11-7-5-4-6-8-11/h4-8H,9-10H2,1-3H3
- IUPAC Standard InChIKey: GRONVOGSDOJOMG-UHFFFAOYSA-N
- CAS Registry Number: 21273-15-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Benzenepropanoic acid, trimethylsilyl ester; Hydrocinnamic acid, trimethylsilyl ester; Trimethylsilyl 3-phenylpropanoate; Dihydrocinnamic acid, TMS; Dihydrocinnamic (benzenepropanoic) acid, TMS
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Van Den Dool and Kratz RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Packed | Packed |
|---|---|---|---|
| Active phase | PE-5 | OV-1 | OV-1 |
| Column length (m) | 30. | 2. | 2. |
| Carrier gas | He | N2 | He |
| Substrate | Supelcoport | Chromosorb W HP (80-100 mesh) | |
| Column diameter (mm) | 0.25 | ||
| Phase thickness (μm) | |||
| Tstart (C) | 50. | 80. | 100. |
| Tend (C) | 250. | 240. | 325. |
| Heat rate (K/min) | 5. | 4. | 10. |
| Initial hold (min) | |||
| Final hold (min) | |||
| I | 1414. | 1397. | 1397. |
| Reference | Isidorov and Vinogorova, 2003 | Mattsson and Petersson, 1977 | Butts, 1972 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Isidorov and Vinogorova, 2003
Isidorov, V.A.; Vinogorova, V.T.,
GC-MS analysis of compounds extracted from buds of Populus balsamifera and Populus nigra,
Z. Naturforsch. C:, 2003, 58, 355-360. [all data]
Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G.,
Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives,
J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546
. [all data]
Butts, 1972
Butts, W.C.,
Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds,
Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3
. [all data]
Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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