Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Reaction data

Iodide + Water = (Iodide bullet Water)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

DeltarH° (kJ/mol) Method Reference Comment
43.5 ± 4.2N/AMarkovich, Giniger, et al., 1991gas phase; For photodissociation of bond plus electron loss, agrees with thermo threshold; B
42.3 ± 4.2TDAsCaldwell and Kebarle, 1984gas phase; B
43.1 ± 1.3TDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
46.44 ± 0.42TDAsKeesee and Castleman, 1980gas phase; B,M
42.68TDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
42.PHPMSCaldwell, Masucci, et al., 1989gas phase; M

References

Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Markovich, Giniger, et al., 1991
Markovich, G.; Giniger, R.; Levin, M.; Cheshnovsky, O., Photoelectron Spectroscopy of Iodine Anion Solvated in Water Clusters, J. Chem. Phys., 1991, 95, 12, 9416, https://doi.org/10.1063/1.461172 . [all data]

Caldwell and Kebarle, 1984
Caldwell, G.; Kebarle, P., Binding energies and structural effects in halide anion-ROH and -RCOOH complexes from gas phase equilibria measurements, J. Am. Chem. Soc., 1984, 106, 967. [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr., Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase, Chem. Phys. Lett., 1980, 74, 139. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]


Notes

Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), References