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Thiazyl fluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to FNS+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)11.51 ± 0.04eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
11.49 ± 0.02PEDixon, Duxbury, et al., 1972LLK
11.54 ± 0.01PEDeKock, Lloyd, et al., 1972LLK
11.36 ± 0.03EIGlemser, Muller, et al., 1968RDSH
11.82PECowan, Gleiter, et al., 1972Vertical value; LLK
11.82PECowan, Gleiter, et al., 1971Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FS+15.5 ± 0.1NEIGlemser, Muller, et al., 1968RDSH
NS+11.80 ± 0.05FEIGlemser, Muller, et al., 1968RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dixon, Duxbury, et al., 1972
Dixon, R.N.; Duxbury, G.; Fleming, G.R.; Hugo, J.M.V., The photoelectron spectrum of thiazyl fluoride, Chem. Phys. Lett., 1972, 14, 60. [all data]

DeKock, Lloyd, et al., 1972
DeKock, R.L.; Lloyd, D.R.; Breeze, A.; Collins, G.A.D.; Cruickshank, D.W.J.; Lempka, H.J., Photoelectron spectroscopy and ab initio LCAO MO SCF calculations on thiazyl fluoride, Chem. Phys. Lett., 1972, 14, 525. [all data]

Glemser, Muller, et al., 1968
Glemser, O.; Muller, A.; Bohler, D.; Krebs, B., Die N-S-Bindung: Bindungslangen Kraftkonstanten, Bindungsgrade und Bindungsenergien, Z. Anorg. Allgem. Chem., 1968, 357, 184. [all data]

Cowan, Gleiter, et al., 1972
Cowan, D.O.; Gleiter, R.; Glemser, O.; Heilbronner, E., The photoelectron spectra of NSCl, NSF NSF3, Helv. Chim. Acta, 1972, 55, 2418. [all data]

Cowan, Gleiter, et al., 1971
Cowan, D.O.; Gleiter, R.; Glemser, O.; Heilbronner, E.; Schaublin, J., The photoelectron spectrum of thiazyl fluoride (NSF), Helv. Chim. Acta, 1971, 54, 1559. [all data]


Notes

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