β-D-Xylopyranose, 4TMS derivative

• Formula: C₁₇H₄₂O₅Si₄
• Molecular weight: 438.8544
• IUPAC Standard InChI: InChI=1S/C17H42O5Si4/c1-23(2,3)19-14-13-18-17(22-26(10,11)12)16(21-25(7,8)9)15(14)20-24(4,5)6/h14-17H,13H2,1-12H3/t14-,15+,16-,17+/m1/s1 Copy

  
• IUPAC Standard InChIKey: KEOUSSOURMHEKN-TWMKSMIVSA-N Copy
• CAS Registry Number: 18623-27-3
• Chemical structure:
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• Stereoisomers:
  • α-D-Xylopyranose, 4TMS derivative
  • A-Lyxopyranose, TMS
  • A-Ribopyranose, TMS
  • B-Arabinopyranose, TMS
  • B-Lyxopyranose, TMS
  • B-Ribopyranose, TMS
  • A-Arabinopyranose, TMS
  • α-D(-)-Lyxose, pyranose, TMS
  • β-D(-)-Lyxose, pyranose, TMS
  • α-D-(-)-Ribopyranose, 4TMS derivative
  • β-D-(-)-Ribopyranose, 4TMS derivative
  • β-D-(+)-Xylopyranose, 4TMS derivative
  • D-Arabinopyranose, 4TMS derivative (isomer 1)
  • D-Arabinopyranose, 4TMS derivative (isomer 2)
  • DL-Arabinopyranose, 4TMS derivative
  • β-D(-)-Lyxopyranose, 4TMS derivative
  • α-D-(-)-Lyxopyranose, 4TMS derivative
• Other names: β-D-Xylopyranose, 1,2,3,4-tetrakis-O-(trimethylsilyl)-; Xylopyranose, 1,2,3,4-tetrakis-O-(trimethylsilyl)-, β-D-; 1,2,3,4-Tetrakis-O-(trimethylsilyl)-β-D-xylopyranose; β-D-Xylopyranose, tetrakis-TMS; β-Xylose, (4TMS); β-Xylopyranose, tetrakis-TMS; D-Xylopyranose, tetrakis(trimethylsilyl) ether; B-Xylopyranose, TMS; β-D-xylopyranose, TMS; D-(+)-Xylose, tetrakis(trimethylsilyl) ether; β-Xylose, TMS
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• Information on this page:
  • Kovats' RI, non-polar column, isothermal
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Options:
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Kovats' RI, non-polar column, isothermal

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

García-Raso, Martínez-Castro, et al., 1987
García-Raso, A.; Martínez-Castro, I.; Páez, M.I.; Sanz, J.; García-Raso, J.; Saura-Calixto, F., Gas Chromatographic Behaviour of Carbohydrate Trimethylsilyl Ethers. I. Aldopentoses, J. Chromatogr., 1987, 398, 9-20, https://doi.org/10.1016/S0021-9673(01)96491-X . [all data]

Paez, Martínez-Castro, et al., 1987
Paez, M.; Martínez-Castro, I.; Sanz, J.; Olano, A.; García-Raso, A.; Saura-Calixto, F., Identification of the components of aldoses in a tautomeric equilibrium mixture as their trimethylsilyl ethers by capillary cas chromatography, Chromatographia, 1987, 23, 1, 43-46, https://doi.org/10.1007/BF02310417 . [all data]

Saura-Calixto, Cañellas, et al., 1984
Saura-Calixto, F.; Cañellas, J.; García-Raso, A., Gas chromatograph analysis of surgars and sugar-alcohols in the mesocarp, endocarp, and kernel of almond fruit, J. Agric. Food Chem., 1984, 32, 5, 1018-1020, https://doi.org/10.1021/jf00125a017 . [all data]

Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References

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